(2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate

The crystal structure of the title compound, C(5)H(8)FNO(2), at 100 K, displays inter­molecular N—H⋯O hydrogen bonding between the ammonium and carboxyl­ate groups as a result of its zwitterionic nature in the solid state. The five-membered ring adopts an envelope conformation with the C atom at the...

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Detalles Bibliográficos
Autores principales: Hobart Jr, David B., Merola, Joseph S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414945/
https://www.ncbi.nlm.nih.gov/pubmed/22904932
http://dx.doi.org/10.1107/S1600536812031741
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author Hobart Jr, David B.
Merola, Joseph S.
author_facet Hobart Jr, David B.
Merola, Joseph S.
author_sort Hobart Jr, David B.
collection PubMed
description The crystal structure of the title compound, C(5)H(8)FNO(2), at 100 K, displays inter­molecular N—H⋯O hydrogen bonding between the ammonium and carboxyl­ate groups as a result of its zwitterionic nature in the solid state. The five-membered ring adopts an envelope conformation with the C atom at the 3-position as the flap. The compound is of inter­est with respect to the synthesis and structural properties of synthetic collagens. The absolute structure was determined by comparison with the commercially available material.
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spelling pubmed-34149452012-08-17 (2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate Hobart Jr, David B. Merola, Joseph S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(5)H(8)FNO(2), at 100 K, displays inter­molecular N—H⋯O hydrogen bonding between the ammonium and carboxyl­ate groups as a result of its zwitterionic nature in the solid state. The five-membered ring adopts an envelope conformation with the C atom at the 3-position as the flap. The compound is of inter­est with respect to the synthesis and structural properties of synthetic collagens. The absolute structure was determined by comparison with the commercially available material. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414945/ /pubmed/22904932 http://dx.doi.org/10.1107/S1600536812031741 Text en © Hobart Jr and Merola 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hobart Jr, David B.
Merola, Joseph S.
(2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate
title (2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate
title_full (2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate
title_fullStr (2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate
title_full_unstemmed (2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate
title_short (2S,4R)-4-Fluoro­pyrrolidinium-2-carboxyl­ate
title_sort (2s,4r)-4-fluoro­pyrrolidinium-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414945/
https://www.ncbi.nlm.nih.gov/pubmed/22904932
http://dx.doi.org/10.1107/S1600536812031741
work_keys_str_mv AT hobartjrdavidb 2s4r4fluoropyrrolidinium2carboxylate
AT merolajosephs 2s4r4fluoropyrrolidinium2carboxylate

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