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2-Eth­oxy-4-(4-methyl­phen­yl)-6-phenyl­pyridine-3-carbonitrile

The title compound, C(21)H(18)N(2)O, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. In mol­ecule A, the central pyridine ring forms dihedral angles of 14.55 (13) and 39.14 (12)° with the terminal phenyl and benzene rings, respectively. The latter rings make a dihedral...

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Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Abdelhamid, Antar A., Singh, Kuldip, El-Remaily, Mahoud A. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414949/
https://www.ncbi.nlm.nih.gov/pubmed/22904936
http://dx.doi.org/10.1107/S1600536812032163
Descripción
Sumario:The title compound, C(21)H(18)N(2)O, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. In mol­ecule A, the central pyridine ring forms dihedral angles of 14.55 (13) and 39.14 (12)° with the terminal phenyl and benzene rings, respectively. The latter rings make a dihedral angle of 33.06 (13)° with each other. The corresponding values for mol­ecule B are 26.86 (13), 41.82 (12) and 38.99 (13)°, respectively. In the crystal, the B mol­ecules are linked via a pair of weak C—H⋯N hydrogen bonds, forming inversion dimers. In addition, C—H⋯π inter­actions and π–π [centroid–centroid distances = 3.5056 (16) and 3.8569 (17) Å] stacking inter­actions are observed.