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(1S,3R,8R)-2,2-Dibromo-3,7,7,10-tetra­methyl­tricyclo­[6.4.0.0(1,3)]dodec-9-ene

The title compound, C(16)H(24)Br(2), was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule is built up from two fused six- and seven-membered rings and an...

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Detalles Bibliográficos
Autores principales: Benharref, Ahmed, El Ammari, Lahcen, Lassaba, Essêdiya, Ourhriss, Najia, Berraho, Moha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414955/
https://www.ncbi.nlm.nih.gov/pubmed/22904942
http://dx.doi.org/10.1107/S1600536812032333
Descripción
Sumario:The title compound, C(16)H(24)Br(2), was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule is built up from two fused six- and seven-membered rings and an additional three-membered ring from the reaction of β-himachalene with dibromo­carbene. The six-membered ring shows a screw-boat conformation, whereas the seven-membered ring displays a boat conformation; the dihedral angle between the mean planes through the rings is 57.9 (4)°. The absolute structure was established unambiguously from anomalous dispersion effects.