1-(6-Bromo-3,4-dihydro-2H-1,4-benz­oxazin-4-yl)-2,2-dichloro­ethanone

The title compound, C(10)H(8)BrCl(2)NO(2), is a target mol­ecule in our research on herbicide safeners. The oxazine ring has an envelope conformation, with puckering parameters close to ideal values [Q = 0.498 (3) Å, θ = 53.7 (3)° and ϕ = 253.4 (4)°]. The crystal structure is stabilized by C—H⋯O, C—...

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Detalles Bibliográficos
Autores principales: Ye, Fei, Li, Ying, Fu, Ying, Zhao, Li-Xia, Gao, Shuang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414960/
https://www.ncbi.nlm.nih.gov/pubmed/22904947
http://dx.doi.org/10.1107/S1600536812032011
Descripción
Sumario:The title compound, C(10)H(8)BrCl(2)NO(2), is a target mol­ecule in our research on herbicide safeners. The oxazine ring has an envelope conformation, with puckering parameters close to ideal values [Q = 0.498 (3) Å, θ = 53.7 (3)° and ϕ = 253.4 (4)°]. The crystal structure is stabilized by C—H⋯O, C—H⋯Cl and C—H⋯Br inter­actions.

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