(3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine

The angles within the benzene ring in the title compound, C(30)H(49)N(3)O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron...

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Detalles Bibliográficos
Autores principales: Spencer, Lara C., Guzei, Ilia A., Ainooson, Michael K., Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414966/
https://www.ncbi.nlm.nih.gov/pubmed/22904953
http://dx.doi.org/10.1107/S160053681203231X
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author Spencer, Lara C.
Guzei, Ilia A.
Ainooson, Michael K.
Darkwa, James
author_facet Spencer, Lara C.
Guzei, Ilia A.
Ainooson, Michael K.
Darkwa, James
author_sort Spencer, Lara C.
collection PubMed
description The angles within the benzene ring in the title compound, C(30)H(49)N(3)O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron-withdrawing eth­oxy substituent larger than 120°, and at the imine substituent equal to 119.59 (16)°. The latter does not reflect the electron-donating nature of the imine group due to the presence of other substituents.
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spelling pubmed-34149662012-08-17 (3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine Spencer, Lara C. Guzei, Ilia A. Ainooson, Michael K. Darkwa, James Acta Crystallogr Sect E Struct Rep Online Organic Papers The angles within the benzene ring in the title compound, C(30)H(49)N(3)O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron-withdrawing eth­oxy substituent larger than 120°, and at the imine substituent equal to 119.59 (16)°. The latter does not reflect the electron-donating nature of the imine group due to the presence of other substituents. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414966/ /pubmed/22904953 http://dx.doi.org/10.1107/S160053681203231X Text en © Spencer et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Spencer, Lara C.
Guzei, Ilia A.
Ainooson, Michael K.
Darkwa, James
(3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine
title (3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine
title_full (3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine
title_fullStr (3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine
title_full_unstemmed (3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine
title_short (3,5-Di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1H-pyrazol-1-yl)eth­yl]amine
title_sort (3,5-di-tert-butyl-2-eth­oxy­benzyl­idene)[2-(3,5-di-tert-butyl-1h-pyrazol-1-yl)eth­yl]amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414966/
https://www.ncbi.nlm.nih.gov/pubmed/22904953
http://dx.doi.org/10.1107/S160053681203231X
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