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9-Allyl-9H-carbazole-3,6-dicarbaldehyde
In the title molecule, C(17)H(13)NO(2), the allyl group is almost perpendicular to the carbazole mean plane, with a dihedral angle of 89.0 (2)°. In the crystal, nonclassical C—H⋯O hydrogen bonds link the molecules into corrugated sheets parallel to the bc plane. Weak intermolecular π–π interacti...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414967/ https://www.ncbi.nlm.nih.gov/pubmed/22904954 http://dx.doi.org/10.1107/S160053681203190X |
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author | Hu, Bin Bin Zeng, Xiang Chao Bian, Lei He, Ru |
author_facet | Hu, Bin Bin Zeng, Xiang Chao Bian, Lei He, Ru |
author_sort | Hu, Bin Bin |
collection | PubMed |
description | In the title molecule, C(17)H(13)NO(2), the allyl group is almost perpendicular to the carbazole mean plane, with a dihedral angle of 89.0 (2)°. In the crystal, nonclassical C—H⋯O hydrogen bonds link the molecules into corrugated sheets parallel to the bc plane. Weak intermolecular π–π interactions are observed between the benzene rings [centroid–centroid distance = 3.874 (4) Å] from neighbouring sheets. |
format | Online Article Text |
id | pubmed-3414967 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34149672012-08-17 9-Allyl-9H-carbazole-3,6-dicarbaldehyde Hu, Bin Bin Zeng, Xiang Chao Bian, Lei He, Ru Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(17)H(13)NO(2), the allyl group is almost perpendicular to the carbazole mean plane, with a dihedral angle of 89.0 (2)°. In the crystal, nonclassical C—H⋯O hydrogen bonds link the molecules into corrugated sheets parallel to the bc plane. Weak intermolecular π–π interactions are observed between the benzene rings [centroid–centroid distance = 3.874 (4) Å] from neighbouring sheets. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414967/ /pubmed/22904954 http://dx.doi.org/10.1107/S160053681203190X Text en © Hu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hu, Bin Bin Zeng, Xiang Chao Bian, Lei He, Ru 9-Allyl-9H-carbazole-3,6-dicarbaldehyde |
title | 9-Allyl-9H-carbazole-3,6-dicarbaldehyde |
title_full | 9-Allyl-9H-carbazole-3,6-dicarbaldehyde |
title_fullStr | 9-Allyl-9H-carbazole-3,6-dicarbaldehyde |
title_full_unstemmed | 9-Allyl-9H-carbazole-3,6-dicarbaldehyde |
title_short | 9-Allyl-9H-carbazole-3,6-dicarbaldehyde |
title_sort | 9-allyl-9h-carbazole-3,6-dicarbaldehyde |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414967/ https://www.ncbi.nlm.nih.gov/pubmed/22904954 http://dx.doi.org/10.1107/S160053681203190X |
work_keys_str_mv | AT hubinbin 9allyl9hcarbazole36dicarbaldehyde AT zengxiangchao 9allyl9hcarbazole36dicarbaldehyde AT bianlei 9allyl9hcarbazole36dicarbaldehyde AT heru 9allyl9hcarbazole36dicarbaldehyde |