(1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate

In the title compound, C(23)H(20)N(2)O(3)·CH(3)OH, the hexa­hydro-1H-benzo[f]isoindole and indoline rings are planar, with maximum deviations of 0.092 (1) and −0.095 (1) Å, respectively. The dihedral angle between these two rings is 88.03 (4)°. An O—H⋯N inter­action links the main mol­ecule and the...

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Autores principales: Sharma, Garima, Kumar, S. Vasanth, Wahab, Habibah A., Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414972/
https://www.ncbi.nlm.nih.gov/pubmed/22904959
http://dx.doi.org/10.1107/S1600536812032643
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author Sharma, Garima
Kumar, S. Vasanth
Wahab, Habibah A.
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Sharma, Garima
Kumar, S. Vasanth
Wahab, Habibah A.
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Sharma, Garima
collection PubMed
description In the title compound, C(23)H(20)N(2)O(3)·CH(3)OH, the hexa­hydro-1H-benzo[f]isoindole and indoline rings are planar, with maximum deviations of 0.092 (1) and −0.095 (1) Å, respectively. The dihedral angle between these two rings is 88.03 (4)°. An O—H⋯N inter­action links the main mol­ecule and the methanol solvent mol­ecule. An intra­molecular C—H⋯O inter­action forms an S(6) ring motif. In the crystal, the mol­ecules form two-dimensional layers parallel to the bc plane through N—H⋯O and C—H⋯O inter­actions.
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spelling pubmed-34149722012-08-17 (1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate Sharma, Garima Kumar, S. Vasanth Wahab, Habibah A. Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(20)N(2)O(3)·CH(3)OH, the hexa­hydro-1H-benzo[f]isoindole and indoline rings are planar, with maximum deviations of 0.092 (1) and −0.095 (1) Å, respectively. The dihedral angle between these two rings is 88.03 (4)°. An O—H⋯N inter­action links the main mol­ecule and the methanol solvent mol­ecule. An intra­molecular C—H⋯O inter­action forms an S(6) ring motif. In the crystal, the mol­ecules form two-dimensional layers parallel to the bc plane through N—H⋯O and C—H⋯O inter­actions. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414972/ /pubmed/22904959 http://dx.doi.org/10.1107/S1600536812032643 Text en © Sharma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sharma, Garima
Kumar, S. Vasanth
Wahab, Habibah A.
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
(1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
title (1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
title_full (1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
title_fullStr (1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
title_full_unstemmed (1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
title_short (1S,3R)-3-Isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
title_sort (1s,3r)-3-isobutyl-2,3-dihydro­spiro[benzo[f]isoindole-1,3′-indoline]-2′,4,9-trione methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414972/
https://www.ncbi.nlm.nih.gov/pubmed/22904959
http://dx.doi.org/10.1107/S1600536812032643
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