2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide

The asymmetric unit of the title compound, C(14)H(13)BrN(2)O, consists of two mol­ecules; the dihedral angles between the pyridine and benzene rings are 87.99 (9) and 84.28 (9)°. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring in each mol­ecule. In the crystal, mol­ecules are linked vi...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Ooi, Chin Wei, Nayak, Prakash S., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414974/
https://www.ncbi.nlm.nih.gov/pubmed/22904961
http://dx.doi.org/10.1107/S1600536812032631
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author Fun, Hoong-Kun
Ooi, Chin Wei
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Ooi, Chin Wei
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(14)H(13)BrN(2)O, consists of two mol­ecules; the dihedral angles between the pyridine and benzene rings are 87.99 (9) and 84.28 (9)°. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring in each mol­ecule. In the crystal, mol­ecules are linked via N—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The crystal structure also features weak π–π stacking inter­actrions between the benzene rings [centroid-to-centroid distance = 3.6829 (12) Å].
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spelling pubmed-34149742012-08-17 2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide Fun, Hoong-Kun Ooi, Chin Wei Nayak, Prakash S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(13)BrN(2)O, consists of two mol­ecules; the dihedral angles between the pyridine and benzene rings are 87.99 (9) and 84.28 (9)°. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring in each mol­ecule. In the crystal, mol­ecules are linked via N—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The crystal structure also features weak π–π stacking inter­actrions between the benzene rings [centroid-to-centroid distance = 3.6829 (12) Å]. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414974/ /pubmed/22904961 http://dx.doi.org/10.1107/S1600536812032631 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Ooi, Chin Wei
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide
title 2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide
title_full 2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide
title_fullStr 2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide
title_full_unstemmed 2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide
title_short 2-(4-Bromo­phen­yl)-N-(5-methyl­pyridin-2-yl)acetamide
title_sort 2-(4-bromo­phen­yl)-n-(5-methyl­pyridin-2-yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414974/
https://www.ncbi.nlm.nih.gov/pubmed/22904961
http://dx.doi.org/10.1107/S1600536812032631
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