2-(2,3-Dimethyl­anilino)benzohydrazide

In the title compound, C(15)H(17)N(3)O, the dihedral angle between the benzene rings is 58.05 (9)°. The non-H atoms of the hydrazide group lie in a common plane (r.m.s. deviation = 0.0006 Å) and are close to coplanar with their attached benzene ring [dihedral angle = 8.02 (9)°]. An intra­molecular N...

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Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Elsaman, Tilal, Attia, Mohamed I., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414975/
https://www.ncbi.nlm.nih.gov/pubmed/22904962
http://dx.doi.org/10.1107/S1600536812032576
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author Fun, Hoong-Kun
Chia, Tze Shyang
Elsaman, Tilal
Attia, Mohamed I.
Abdel-Aziz, Hatem A.
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Elsaman, Tilal
Attia, Mohamed I.
Abdel-Aziz, Hatem A.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(15)H(17)N(3)O, the dihedral angle between the benzene rings is 58.05 (9)°. The non-H atoms of the hydrazide group lie in a common plane (r.m.s. deviation = 0.0006 Å) and are close to coplanar with their attached benzene ring [dihedral angle = 8.02 (9)°]. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif in the mol­ecule, and a short intra­molecular contact (H⋯H = 1.88 Å) is also observed. In the crystal, mol­ecules are linked by pairs of N—H⋯N hydrogen bonds into inversion dimers. The crystal packing also features C—H⋯π inter­actions.
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spelling pubmed-34149752012-08-17 2-(2,3-Dimethyl­anilino)benzohydrazide Fun, Hoong-Kun Chia, Tze Shyang Elsaman, Tilal Attia, Mohamed I. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(17)N(3)O, the dihedral angle between the benzene rings is 58.05 (9)°. The non-H atoms of the hydrazide group lie in a common plane (r.m.s. deviation = 0.0006 Å) and are close to coplanar with their attached benzene ring [dihedral angle = 8.02 (9)°]. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif in the mol­ecule, and a short intra­molecular contact (H⋯H = 1.88 Å) is also observed. In the crystal, mol­ecules are linked by pairs of N—H⋯N hydrogen bonds into inversion dimers. The crystal packing also features C—H⋯π inter­actions. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414975/ /pubmed/22904962 http://dx.doi.org/10.1107/S1600536812032576 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Elsaman, Tilal
Attia, Mohamed I.
Abdel-Aziz, Hatem A.
2-(2,3-Dimethyl­anilino)benzohydrazide
title 2-(2,3-Dimethyl­anilino)benzohydrazide
title_full 2-(2,3-Dimethyl­anilino)benzohydrazide
title_fullStr 2-(2,3-Dimethyl­anilino)benzohydrazide
title_full_unstemmed 2-(2,3-Dimethyl­anilino)benzohydrazide
title_short 2-(2,3-Dimethyl­anilino)benzohydrazide
title_sort 2-(2,3-dimethyl­anilino)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414975/
https://www.ncbi.nlm.nih.gov/pubmed/22904962
http://dx.doi.org/10.1107/S1600536812032576
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AT elsamantilal 223dimethylanilinobenzohydrazide
AT attiamohamedi 223dimethylanilinobenzohydrazide
AT abdelazizhatema 223dimethylanilinobenzohydrazide

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