6-[4-(Diphenyl­amino)­phen­yl]quinoline 1-oxide

In the title mol­ecule, C(27)H(20)N(2)O, a triphenyl­amine derivative of quinoline, the three benzene rings linked through an N atom form a propeller shape, with dihedral angles between the mean planes of pairs of rings of 75.57 (9), 55.68 (9) and 83.66 (9)°. The quinoline ring is essentially planar...

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Detalles Bibliográficos
Autores principales: Wang, Li-Zhi, Chi, Yun, Li, Xiang-Xiang, Guan, Jian-Ning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414988/
https://www.ncbi.nlm.nih.gov/pubmed/22904975
http://dx.doi.org/10.1107/S1600536812031662
Descripción
Sumario:In the title mol­ecule, C(27)H(20)N(2)O, a triphenyl­amine derivative of quinoline, the three benzene rings linked through an N atom form a propeller shape, with dihedral angles between the mean planes of pairs of rings of 75.57 (9), 55.68 (9) and 83.66 (9)°. The quinoline ring is essentially planar, with an r.m.s. deviation of the fitted atoms of 0.0155 Å, and forms a dihedral angle of 33.52 (8)° with the benzene ring to which it is bonded. Weak C—H⋯π inter­actions are also observed in the crystal structure.

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