(R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate

The title compound, C(22)H(16)ClNO(4), adopts a conformation in which the phenyl ring plane forms similar dihedral angles with the nitro­benzoate C(6) ring [76.97 (8)°] and the chloro­phenyl group [76.95 (8)°]; the dihedral angle between the chloro­phenyl and nitro­benzoate rings is 66.43 (8)°. In t...

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Detalles Bibliográficos
Autores principales: Troshin, Konstantin, Mayer, Peter, Mayr, Herbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414994/
https://www.ncbi.nlm.nih.gov/pubmed/22904981
http://dx.doi.org/10.1107/S1600536812032813
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author Troshin, Konstantin
Mayer, Peter
Mayr, Herbert
author_facet Troshin, Konstantin
Mayer, Peter
Mayr, Herbert
author_sort Troshin, Konstantin
collection PubMed
description The title compound, C(22)H(16)ClNO(4), adopts a conformation in which the phenyl ring plane forms similar dihedral angles with the nitro­benzoate C(6) ring [76.97 (8)°] and the chloro­phenyl group [76.95 (8)°]; the dihedral angle between the chloro­phenyl and nitro­benzoate rings is 66.43 (8)°. In the crystal, π–π stacking is observed between the latter two planes, with a dihedral angle of 1.79 (8)° and a centroid–centroid distance of 3.735 (1) Å. In addition, mol­ecules are linked along [100] by weak C—H⋯O contacts.
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spelling pubmed-34149942012-08-17 (R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate Troshin, Konstantin Mayer, Peter Mayr, Herbert Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(16)ClNO(4), adopts a conformation in which the phenyl ring plane forms similar dihedral angles with the nitro­benzoate C(6) ring [76.97 (8)°] and the chloro­phenyl group [76.95 (8)°]; the dihedral angle between the chloro­phenyl and nitro­benzoate rings is 66.43 (8)°. In the crystal, π–π stacking is observed between the latter two planes, with a dihedral angle of 1.79 (8)° and a centroid–centroid distance of 3.735 (1) Å. In addition, mol­ecules are linked along [100] by weak C—H⋯O contacts. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414994/ /pubmed/22904981 http://dx.doi.org/10.1107/S1600536812032813 Text en © Troshin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Troshin, Konstantin
Mayer, Peter
Mayr, Herbert
(R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
title (R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
title_full (R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
title_fullStr (R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
title_full_unstemmed (R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
title_short (R,E)-3-(4-Chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
title_sort (r,e)-3-(4-chloro­phen­yl)-1-phenyl­allyl 4-nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414994/
https://www.ncbi.nlm.nih.gov/pubmed/22904981
http://dx.doi.org/10.1107/S1600536812032813
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