Melaminium hydrogen malonate

The melaminium (2,4,6-triamino-1,3,5-triazin-1-ium) cation in the title compound, C(3)H(7)N(6) (+)·C(3)H(3)O(4) (−), is essentially planar, with a r.m.s. deviation of the non-H atoms of 0.0085 Å. Extensive hydrogen bonding of the types N—H⋯N and N—H⋯O between cations and cations and between cations...

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Detalles Bibliográficos
Autores principales: Froschauer, Barbara, Weil, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414997/
https://www.ncbi.nlm.nih.gov/pubmed/22904984
http://dx.doi.org/10.1107/S1600536812033016
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author Froschauer, Barbara
Weil, Matthias
author_facet Froschauer, Barbara
Weil, Matthias
author_sort Froschauer, Barbara
collection PubMed
description The melaminium (2,4,6-triamino-1,3,5-triazin-1-ium) cation in the title compound, C(3)H(7)N(6) (+)·C(3)H(3)O(4) (−), is essentially planar, with a r.m.s. deviation of the non-H atoms of 0.0085 Å. Extensive hydrogen bonding of the types N—H⋯N and N—H⋯O between cations and cations and between cations and hydrogen malonate (2-carb­oxy­ethano­ate) anions leads to the formation of supra­molecular layers parallel to (1-2-1). An intra­molecular O—H⋯O hydrogen bond in the single deprotonated malonate anion also occurs.
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spelling pubmed-34149972012-08-17 Melaminium hydrogen malonate Froschauer, Barbara Weil, Matthias Acta Crystallogr Sect E Struct Rep Online Organic Papers The melaminium (2,4,6-triamino-1,3,5-triazin-1-ium) cation in the title compound, C(3)H(7)N(6) (+)·C(3)H(3)O(4) (−), is essentially planar, with a r.m.s. deviation of the non-H atoms of 0.0085 Å. Extensive hydrogen bonding of the types N—H⋯N and N—H⋯O between cations and cations and between cations and hydrogen malonate (2-carb­oxy­ethano­ate) anions leads to the formation of supra­molecular layers parallel to (1-2-1). An intra­molecular O—H⋯O hydrogen bond in the single deprotonated malonate anion also occurs. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414997/ /pubmed/22904984 http://dx.doi.org/10.1107/S1600536812033016 Text en © Froschauer and Weil 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Froschauer, Barbara
Weil, Matthias
Melaminium hydrogen malonate
title Melaminium hydrogen malonate
title_full Melaminium hydrogen malonate
title_fullStr Melaminium hydrogen malonate
title_full_unstemmed Melaminium hydrogen malonate
title_short Melaminium hydrogen malonate
title_sort melaminium hydrogen malonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414997/
https://www.ncbi.nlm.nih.gov/pubmed/22904984
http://dx.doi.org/10.1107/S1600536812033016
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