3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate

In the anion of the title molecular salt, C(6)H(9)BNO(2) (+)·C(7)H(4)NO(4) (−), the dihedral angles between the –COO(2−) and –CO(2)H groups and their attached ring are 4.02 (13) and 21.41 (10)°, respectively. The B atom in the cation adopts a syn–syn geometry and the dihedral angle between the –B(OH...

Descripción completa

Detalles Bibliográficos
Autores principales: Ge, Chunhua, Zhang, Xiangdong, Zhang, Rui, Zhang, Chenglong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415001/
https://www.ncbi.nlm.nih.gov/pubmed/22904988
http://dx.doi.org/10.1107/S1600536812031790
_version_ 1782240297790472192
author Ge, Chunhua
Zhang, Xiangdong
Zhang, Rui
Zhang, Chenglong
author_facet Ge, Chunhua
Zhang, Xiangdong
Zhang, Rui
Zhang, Chenglong
author_sort Ge, Chunhua
collection PubMed
description In the anion of the title molecular salt, C(6)H(9)BNO(2) (+)·C(7)H(4)NO(4) (−), the dihedral angles between the –COO(2−) and –CO(2)H groups and their attached ring are 4.02 (13) and 21.41 (10)°, respectively. The B atom in the cation adopts a syn–syn geometry and the dihedral angle between the –B(OH)(2) group and its attached ring is 11.06 (5)°. In the crystal, O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds link the components into a three-dimensional network.
format Online
Article
Text
id pubmed-3415001
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34150012012-08-17 3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate Ge, Chunhua Zhang, Xiangdong Zhang, Rui Zhang, Chenglong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the anion of the title molecular salt, C(6)H(9)BNO(2) (+)·C(7)H(4)NO(4) (−), the dihedral angles between the –COO(2−) and –CO(2)H groups and their attached ring are 4.02 (13) and 21.41 (10)°, respectively. The B atom in the cation adopts a syn–syn geometry and the dihedral angle between the –B(OH)(2) group and its attached ring is 11.06 (5)°. In the crystal, O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds link the components into a three-dimensional network. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3415001/ /pubmed/22904988 http://dx.doi.org/10.1107/S1600536812031790 Text en © Ge et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ge, Chunhua
Zhang, Xiangdong
Zhang, Rui
Zhang, Chenglong
3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
title 3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
title_full 3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
title_fullStr 3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
title_full_unstemmed 3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
title_short 3-(Dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
title_sort 3-(dihy­droxy­bor­yl)anilinium 6-carb­oxy­pyridine-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415001/
https://www.ncbi.nlm.nih.gov/pubmed/22904988
http://dx.doi.org/10.1107/S1600536812031790
work_keys_str_mv AT gechunhua 3dihydroxyborylanilinium6carboxypyridine2carboxylate
AT zhangxiangdong 3dihydroxyborylanilinium6carboxypyridine2carboxylate
AT zhangrui 3dihydroxyborylanilinium6carboxypyridine2carboxylate
AT zhangchenglong 3dihydroxyborylanilinium6carboxypyridine2carboxylate

Ejemplares similares