2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate

In the title compound, C(19)H(15)N(4) (+)·Br(−)·C(2)H(5)OH, the tetra­zole ring makes dihedral angles of 57.44 (9), 50.92 (9) and 4.65 (8)° with the attached phenyl rings. In the crystal, the cation and the anion are linked to each other by inter­molecular C—H⋯Br hydrogen bonds into an infinite chai...

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Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Mostafa, Gamal A. E., Hefnawy, Mohamed M., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415007/
https://www.ncbi.nlm.nih.gov/pubmed/22904994
http://dx.doi.org/10.1107/S1600536812032953
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author Fun, Hoong-Kun
Chia, Tze Shyang
Mostafa, Gamal A. E.
Hefnawy, Mohamed M.
Abdel-Aziz, Hatem A.
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Mostafa, Gamal A. E.
Hefnawy, Mohamed M.
Abdel-Aziz, Hatem A.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(19)H(15)N(4) (+)·Br(−)·C(2)H(5)OH, the tetra­zole ring makes dihedral angles of 57.44 (9), 50.92 (9) and 4.65 (8)° with the attached phenyl rings. In the crystal, the cation and the anion are linked to each other by inter­molecular C—H⋯Br hydrogen bonds into an infinite chain along the b axis. The anion and the ethanol solvent mol­ecule are linked by an O—H⋯Br hydrogen bond. The crystal studied was an inversion twin with a refined component ratio of 0.632 (5):0.368 (5).
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spelling pubmed-34150072012-08-17 2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate Fun, Hoong-Kun Chia, Tze Shyang Mostafa, Gamal A. E. Hefnawy, Mohamed M. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(15)N(4) (+)·Br(−)·C(2)H(5)OH, the tetra­zole ring makes dihedral angles of 57.44 (9), 50.92 (9) and 4.65 (8)° with the attached phenyl rings. In the crystal, the cation and the anion are linked to each other by inter­molecular C—H⋯Br hydrogen bonds into an infinite chain along the b axis. The anion and the ethanol solvent mol­ecule are linked by an O—H⋯Br hydrogen bond. The crystal studied was an inversion twin with a refined component ratio of 0.632 (5):0.368 (5). International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415007/ /pubmed/22904994 http://dx.doi.org/10.1107/S1600536812032953 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Mostafa, Gamal A. E.
Hefnawy, Mohamed M.
Abdel-Aziz, Hatem A.
2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate
title 2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate
title_full 2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate
title_fullStr 2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate
title_full_unstemmed 2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate
title_short 2,3,5-Triphenyl-2H-tetra­zol-3-ium bromide ethanol monosolvate
title_sort 2,3,5-triphenyl-2h-tetra­zol-3-ium bromide ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415007/
https://www.ncbi.nlm.nih.gov/pubmed/22904994
http://dx.doi.org/10.1107/S1600536812032953
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