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2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate
In the title salt, C(19)H(15)N(4) (+)·C(24)H(20)B(−), the tetraphenylborate anion is in a tetrahedral geometry around the B atom [C—B—C angles of 107.10 (9)–111.79 (9)°]. In the cation, the tetrazole ring makes dihedral angles of 3.04 (7), 51.75 (7) and 51.13 (7)° with the attached phenyl rings....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415008/ https://www.ncbi.nlm.nih.gov/pubmed/22904995 http://dx.doi.org/10.1107/S1600536812032941 |
| _version_ | 1782240299402133504 |
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| author | Fun, Hoong-Kun Chia, Tze Shyang Mostafa, Gamal A. E. Hefnawy, Mohamed M. Abdel-Aziz, Hatem A. |
| author_facet | Fun, Hoong-Kun Chia, Tze Shyang Mostafa, Gamal A. E. Hefnawy, Mohamed M. Abdel-Aziz, Hatem A. |
| author_sort | Fun, Hoong-Kun |
| collection | PubMed |
| description | In the title salt, C(19)H(15)N(4) (+)·C(24)H(20)B(−), the tetraphenylborate anion is in a tetrahedral geometry around the B atom [C—B—C angles of 107.10 (9)–111.79 (9)°]. In the cation, the tetrazole ring makes dihedral angles of 3.04 (7), 51.75 (7) and 51.13 (7)° with the attached phenyl rings. In the crystal, C—H⋯π interactions link the cations and anions into ion pairs. |
| format | Online Article Text |
| id | pubmed-3415008 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34150082012-08-17 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate Fun, Hoong-Kun Chia, Tze Shyang Mostafa, Gamal A. E. Hefnawy, Mohamed M. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(19)H(15)N(4) (+)·C(24)H(20)B(−), the tetraphenylborate anion is in a tetrahedral geometry around the B atom [C—B—C angles of 107.10 (9)–111.79 (9)°]. In the cation, the tetrazole ring makes dihedral angles of 3.04 (7), 51.75 (7) and 51.13 (7)° with the attached phenyl rings. In the crystal, C—H⋯π interactions link the cations and anions into ion pairs. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415008/ /pubmed/22904995 http://dx.doi.org/10.1107/S1600536812032941 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Fun, Hoong-Kun Chia, Tze Shyang Mostafa, Gamal A. E. Hefnawy, Mohamed M. Abdel-Aziz, Hatem A. 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate |
| title | 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate |
| title_full | 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate |
| title_fullStr | 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate |
| title_full_unstemmed | 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate |
| title_short | 2,3,5-Triphenyl-2H-tetrazol-3-ium tetraphenylborate |
| title_sort | 2,3,5-triphenyl-2h-tetrazol-3-ium tetraphenylborate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415008/ https://www.ncbi.nlm.nih.gov/pubmed/22904995 http://dx.doi.org/10.1107/S1600536812032941 |
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