4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid

In the title compound, C(12)H(16)N(2)O(6)S, the S atom adopts a distorted tetra­hedral geometry with an O—S—O angle of 119.76 (13)°. The nitro group is twisted by 35.34 (2)° with respect to the aromatic ring; it accepts an N—H⋯O hydrogen bond, resulting in a S(7) motif. In the crystal, N—H⋯O and O—H...

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Autores principales: Arshad, Muhammad Nadeem, Danish, Muhammad, Tahir, Muhammad Nawaz, Khalid, Savera, Asiri, Abdullah M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415013/
https://www.ncbi.nlm.nih.gov/pubmed/22905000
http://dx.doi.org/10.1107/S1600536812033260
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author Arshad, Muhammad Nadeem
Danish, Muhammad
Tahir, Muhammad Nawaz
Khalid, Savera
Asiri, Abdullah M.
author_facet Arshad, Muhammad Nadeem
Danish, Muhammad
Tahir, Muhammad Nawaz
Khalid, Savera
Asiri, Abdullah M.
author_sort Arshad, Muhammad Nadeem
collection PubMed
description In the title compound, C(12)H(16)N(2)O(6)S, the S atom adopts a distorted tetra­hedral geometry with an O—S—O angle of 119.76 (13)°. The nitro group is twisted by 35.34 (2)° with respect to the aromatic ring; it accepts an N—H⋯O hydrogen bond, resulting in a S(7) motif. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds connect the mol­ecules into an infinite chain along the a axis. The methyl C atoms of the isopropyl group are disordered in a 1:1 ratio.
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spelling pubmed-34150132012-08-17 4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid Arshad, Muhammad Nadeem Danish, Muhammad Tahir, Muhammad Nawaz Khalid, Savera Asiri, Abdullah M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(16)N(2)O(6)S, the S atom adopts a distorted tetra­hedral geometry with an O—S—O angle of 119.76 (13)°. The nitro group is twisted by 35.34 (2)° with respect to the aromatic ring; it accepts an N—H⋯O hydrogen bond, resulting in a S(7) motif. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds connect the mol­ecules into an infinite chain along the a axis. The methyl C atoms of the isopropyl group are disordered in a 1:1 ratio. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415013/ /pubmed/22905000 http://dx.doi.org/10.1107/S1600536812033260 Text en © Arshad et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Muhammad Nadeem
Danish, Muhammad
Tahir, Muhammad Nawaz
Khalid, Savera
Asiri, Abdullah M.
4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
title 4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
title_full 4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
title_fullStr 4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
title_full_unstemmed 4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
title_short 4-Methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
title_sort 4-methyl-2-(2-nitro­benzene­sulfon­amido)­penta­noic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415013/
https://www.ncbi.nlm.nih.gov/pubmed/22905000
http://dx.doi.org/10.1107/S1600536812033260
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