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3-Acetyl-1-(3-methyl­phen­yl)thio­urea

In the crystal structure of the title compound, C(10)H(12)N(2)OS, the conformation of the two N—H bonds are anti to each other. The amide C=O and the C=S are are also anti to each other. The N—H bond adjacent to the benzene ring is syn to the m-methyl groups. The dihedral angle between the benzene r...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Kumar, Sharatha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415014/
https://www.ncbi.nlm.nih.gov/pubmed/22905001
http://dx.doi.org/10.1107/S1600536812032825
Descripción
Sumario:In the crystal structure of the title compound, C(10)H(12)N(2)OS, the conformation of the two N—H bonds are anti to each other. The amide C=O and the C=S are are also anti to each other. The N—H bond adjacent to the benzene ring is syn to the m-methyl groups. The dihedral angle between the benzene ring and the side chain [mean plane of atoms C—C(O)N—C—N; maximum deviation 0.029 (2) Å] is 14.30 (7)°. There is an intramolecular N—H⋯O hydrogen bond generating an S(6) ring motif. In the crystal, the molecules are linked via N—H⋯) hydrogen bonds, forming chains propagating along [001]. The S atom is disordered and was refined using a split model [occupancy ratio 0.56 (4):0.44 (4)].