N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide

In the title compound, C(12)H(9)ClN(2)O(4)S, the N—H bond in the –SO(2)—NH– segment is syn to both the ortho-nitro group in the sulfonyl­benzene ring and the ortho-Cl atom in the aniline ring. The mol­ecule is twisted at the S—N bond with a torsion angle of 75.0 (2)°. The dihedral angle between the...

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Detalles Bibliográficos
Autores principales: Chaithanya, U., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415015/
https://www.ncbi.nlm.nih.gov/pubmed/22905002
http://dx.doi.org/10.1107/S1600536812033107
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author Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_facet Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_sort Chaithanya, U.
collection PubMed
description In the title compound, C(12)H(9)ClN(2)O(4)S, the N—H bond in the –SO(2)—NH– segment is syn to both the ortho-nitro group in the sulfonyl­benzene ring and the ortho-Cl atom in the aniline ring. The mol­ecule is twisted at the S—N bond with a torsion angle of 75.0 (2)°. The dihedral angle between the sulfonyl­benzene and aniline rings is 54.97 (11)°. The amide H atom shows bifurcated hydrogen bonding, generating S(7) and C(4) motifs. In the crystal, N—H⋯O(S) hydrogen bonds link the mol­ecules into chains.
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spelling pubmed-34150152012-08-17 N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide Chaithanya, U. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(9)ClN(2)O(4)S, the N—H bond in the –SO(2)—NH– segment is syn to both the ortho-nitro group in the sulfonyl­benzene ring and the ortho-Cl atom in the aniline ring. The mol­ecule is twisted at the S—N bond with a torsion angle of 75.0 (2)°. The dihedral angle between the sulfonyl­benzene and aniline rings is 54.97 (11)°. The amide H atom shows bifurcated hydrogen bonding, generating S(7) and C(4) motifs. In the crystal, N—H⋯O(S) hydrogen bonds link the mol­ecules into chains. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415015/ /pubmed/22905002 http://dx.doi.org/10.1107/S1600536812033107 Text en © Chaithanya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide
title N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide
title_full N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide
title_fullStr N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide
title_full_unstemmed N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide
title_short N-(2-Chloro­phen­yl)-2-nitro­benzene­sulfonamide
title_sort n-(2-chloro­phen­yl)-2-nitro­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415015/
https://www.ncbi.nlm.nih.gov/pubmed/22905002
http://dx.doi.org/10.1107/S1600536812033107
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AT forosabine n2chlorophenyl2nitrobenzenesulfonamide
AT gowdabthimme n2chlorophenyl2nitrobenzenesulfonamide

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