(Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone

The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)° with the benzothio­phene system ring. The benzothio­phene system and the remaining phenyl ring make an angle of 12.71 (13)°. The conformation around the imine functions is E for...

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Autores principales: Pekdemir, Merve, Işık, Şamil, Gümüş, Sümeyye, Ağar, Erbil, Soylu, Mustafa Serkan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415019/
https://www.ncbi.nlm.nih.gov/pubmed/22905006
http://dx.doi.org/10.1107/S1600536812030978
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author Pekdemir, Merve
Işık, Şamil
Gümüş, Sümeyye
Ağar, Erbil
Soylu, Mustafa Serkan
author_facet Pekdemir, Merve
Işık, Şamil
Gümüş, Sümeyye
Ağar, Erbil
Soylu, Mustafa Serkan
author_sort Pekdemir, Merve
collection PubMed
description The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)° with the benzothio­phene system ring. The benzothio­phene system and the remaining phenyl ring make an angle of 12.71 (13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio­phene system and Z for the C=N bond towards the benzoyl group. The packing of the mol­ecules shows C—H⋯π inter­actions. A weak intramolecular C—H⋯N bond also occurs.
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spelling pubmed-34150192012-08-17 (Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone Pekdemir, Merve Işık, Şamil Gümüş, Sümeyye Ağar, Erbil Soylu, Mustafa Serkan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)° with the benzothio­phene system ring. The benzothio­phene system and the remaining phenyl ring make an angle of 12.71 (13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio­phene system and Z for the C=N bond towards the benzoyl group. The packing of the mol­ecules shows C—H⋯π inter­actions. A weak intramolecular C—H⋯N bond also occurs. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415019/ /pubmed/22905006 http://dx.doi.org/10.1107/S1600536812030978 Text en © Pekdemir et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pekdemir, Merve
Işık, Şamil
Gümüş, Sümeyye
Ağar, Erbil
Soylu, Mustafa Serkan
(Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
title (Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
title_full (Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
title_fullStr (Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
title_full_unstemmed (Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
title_short (Z)-2-[(E)-2-(1-Benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
title_sort (z)-2-[(e)-2-(1-benzothio­phen-3-yl­methyl­idene)hydrazin-1-yl­idene]-1,2-diphenyl­ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415019/
https://www.ncbi.nlm.nih.gov/pubmed/22905006
http://dx.doi.org/10.1107/S1600536812030978
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