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2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide
The molecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothioamide substituent and t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415020/ https://www.ncbi.nlm.nih.gov/pubmed/22905007 http://dx.doi.org/10.1107/S1600536812033302 |
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author | de Oliveira, Adriano Bof Silva, Cecília Santos Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke |
author_facet | de Oliveira, Adriano Bof Silva, Cecília Santos Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke |
author_sort | de Oliveira, Adriano Bof |
collection | PubMed |
description | The molecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothioamide substituent and the benzene ring have maximum deviations from the mean planes through the non-H atoms of 0.0288 (16) and 0.0124 (27) Å, respectively, and the dihedral angle between the two planes is 8.84 (13)°. In the crystal, molecules are linked into chains along [1[Image: see text]0] by pairs of N—H⋯S hydrogen bonds between molecules related by centres of symmetry. |
format | Online Article Text |
id | pubmed-3415020 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34150202012-08-17 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide de Oliveira, Adriano Bof Silva, Cecília Santos Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothioamide substituent and the benzene ring have maximum deviations from the mean planes through the non-H atoms of 0.0288 (16) and 0.0124 (27) Å, respectively, and the dihedral angle between the two planes is 8.84 (13)°. In the crystal, molecules are linked into chains along [1[Image: see text]0] by pairs of N—H⋯S hydrogen bonds between molecules related by centres of symmetry. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415020/ /pubmed/22905007 http://dx.doi.org/10.1107/S1600536812033302 Text en © Oliveira et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers de Oliveira, Adriano Bof Silva, Cecília Santos Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title | 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_full | 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_fullStr | 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_full_unstemmed | 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_short | 2-(1,2,3,4-Tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
title_sort | 2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415020/ https://www.ncbi.nlm.nih.gov/pubmed/22905007 http://dx.doi.org/10.1107/S1600536812033302 |
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