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2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide

The mol­ecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothio­amide substituent and t...

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Autores principales: de Oliveira, Adriano Bof, Silva, Cecília Santos, Feitosa, Bárbara Regina Santos, Näther, Christian, Jess, Inke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415020/
https://www.ncbi.nlm.nih.gov/pubmed/22905007
http://dx.doi.org/10.1107/S1600536812033302
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author de Oliveira, Adriano Bof
Silva, Cecília Santos
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_facet de Oliveira, Adriano Bof
Silva, Cecília Santos
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_sort de Oliveira, Adriano Bof
collection PubMed
description The mol­ecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothio­amide substituent and the benzene ring have maximum deviations from the mean planes through the non-H atoms of 0.0288 (16) and 0.0124 (27) Å, respectively, and the dihedral angle between the two planes is 8.84 (13)°. In the crystal, mol­ecules are linked into chains along [1[Image: see text]0] by pairs of N—H⋯S hydrogen bonds between mol­ecules related by centres of symmetry.
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spelling pubmed-34150202012-08-17 2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide de Oliveira, Adriano Bof Silva, Cecília Santos Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothio­amide substituent and the benzene ring have maximum deviations from the mean planes through the non-H atoms of 0.0288 (16) and 0.0124 (27) Å, respectively, and the dihedral angle between the two planes is 8.84 (13)°. In the crystal, mol­ecules are linked into chains along [1[Image: see text]0] by pairs of N—H⋯S hydrogen bonds between mol­ecules related by centres of symmetry. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415020/ /pubmed/22905007 http://dx.doi.org/10.1107/S1600536812033302 Text en © Oliveira et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Oliveira, Adriano Bof
Silva, Cecília Santos
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
title 2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
title_full 2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
title_fullStr 2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
title_full_unstemmed 2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
title_short 2-(1,2,3,4-Tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
title_sort 2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415020/
https://www.ncbi.nlm.nih.gov/pubmed/22905007
http://dx.doi.org/10.1107/S1600536812033302
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