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2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)

The title co-crystal, 0.95C(20)H(20)O(3)·0.05C(20)H(19)ClO(3), arises as the chloride carried over during the synthesis shares a position with an aromatic H atom; the partial occupancies are 0.947 (2) and 0.053 (2) for H and Cl, respectively. The mol­ecular structure is stabilized by intra­molecular...

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Detalles Bibliográficos
Autores principales: Barot, Vijay M., Jotani, Mukesh M., Maheta, Jeshal G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415021/
https://www.ncbi.nlm.nih.gov/pubmed/22905008
http://dx.doi.org/10.1107/S1600536812033430
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author Barot, Vijay M.
Jotani, Mukesh M.
Maheta, Jeshal G.
author_facet Barot, Vijay M.
Jotani, Mukesh M.
Maheta, Jeshal G.
author_sort Barot, Vijay M.
collection PubMed
description The title co-crystal, 0.95C(20)H(20)O(3)·0.05C(20)H(19)ClO(3), arises as the chloride carried over during the synthesis shares a position with an aromatic H atom; the partial occupancies are 0.947 (2) and 0.053 (2) for H and Cl, respectively. The mol­ecular structure is stabilized by intra­molecular C—H⋯O contacts, forming pseudo five- and six-membered rings with S(5) and S(6) graph-set motifs, respectively. The crystal structure features π–π stacking inter­actions between the centroids of the central fused ring systems [centroid–centroid distance = 3.501 (2) Å].
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spelling pubmed-34150212012-08-17 2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1) Barot, Vijay M. Jotani, Mukesh M. Maheta, Jeshal G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title co-crystal, 0.95C(20)H(20)O(3)·0.05C(20)H(19)ClO(3), arises as the chloride carried over during the synthesis shares a position with an aromatic H atom; the partial occupancies are 0.947 (2) and 0.053 (2) for H and Cl, respectively. The mol­ecular structure is stabilized by intra­molecular C—H⋯O contacts, forming pseudo five- and six-membered rings with S(5) and S(6) graph-set motifs, respectively. The crystal structure features π–π stacking inter­actions between the centroids of the central fused ring systems [centroid–centroid distance = 3.501 (2) Å]. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415021/ /pubmed/22905008 http://dx.doi.org/10.1107/S1600536812033430 Text en © Barot et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Barot, Vijay M.
Jotani, Mukesh M.
Maheta, Jeshal G.
2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)
title 2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)
title_full 2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)
title_fullStr 2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)
title_full_unstemmed 2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)
title_short 2-(4-Methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4H-chromen-4-one (19/1)
title_sort 2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4h-chromen-4-one–6-chloro-2-(4-methyl­phen­yl)-7-(2-methyl­prop­oxy)-4h-chromen-4-one (19/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415021/
https://www.ncbi.nlm.nih.gov/pubmed/22905008
http://dx.doi.org/10.1107/S1600536812033430
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