1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene

The title compound, C(38)H(30)N(4), a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmeth­yl)benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09 (5)° angle between...

Descripción completa

Detalles Bibliográficos
Autores principales: Spencer, Lara C., Guzei, Ilia A., Segapelo, Tebogo V., Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415022/
https://www.ncbi.nlm.nih.gov/pubmed/22905009
http://dx.doi.org/10.1107/S1600536812032801
_version_ 1782240302612873216
author Spencer, Lara C.
Guzei, Ilia A.
Segapelo, Tebogo V.
Darkwa, James
author_facet Spencer, Lara C.
Guzei, Ilia A.
Segapelo, Tebogo V.
Darkwa, James
author_sort Spencer, Lara C.
collection PubMed
description The title compound, C(38)H(30)N(4), a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmeth­yl)benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09 (5)° angle between their mean planes and exhibit a trans-like geometry in which the in-plane lone pairs of electrons on the 2-N nitrogen atoms point in opposite directions.
format Online
Article
Text
id pubmed-3415022
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34150222012-08-17 1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene Spencer, Lara C. Guzei, Ilia A. Segapelo, Tebogo V. Darkwa, James Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(38)H(30)N(4), a potentially mono- and bidentate ligand, does not seem to form palladium complexes similar to other poly(pyrazol-1-ylmeth­yl)benzenes due to the large steric size of the phenyl substituents on the pyrazole rings. The pyrazole rings have a 21.09 (5)° angle between their mean planes and exhibit a trans-like geometry in which the in-plane lone pairs of electrons on the 2-N nitrogen atoms point in opposite directions. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415022/ /pubmed/22905009 http://dx.doi.org/10.1107/S1600536812032801 Text en © Spencer et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Spencer, Lara C.
Guzei, Ilia A.
Segapelo, Tebogo V.
Darkwa, James
1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene
title 1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene
title_full 1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene
title_fullStr 1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene
title_full_unstemmed 1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene
title_short 1,2-Bis[(3,5-diphenyl-1H-pyrazol-1-yl)meth­yl]benzene
title_sort 1,2-bis[(3,5-diphenyl-1h-pyrazol-1-yl)meth­yl]benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415022/
https://www.ncbi.nlm.nih.gov/pubmed/22905009
http://dx.doi.org/10.1107/S1600536812032801
work_keys_str_mv AT spencerlarac 12bis35diphenyl1hpyrazol1ylmethylbenzene
AT guzeiiliaa 12bis35diphenyl1hpyrazol1ylmethylbenzene
AT segapelotebogov 12bis35diphenyl1hpyrazol1ylmethylbenzene
AT darkwajames 12bis35diphenyl1hpyrazol1ylmethylbenzene

Ejemplares similares