4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate

In the title compound, C(30)H(26)O(6)·C(3)H(6)O, the syn-oriented benzoyl groups are nearly parallel to each other; the dihedral angle between their benzene rings is 15.9 (1)°. They form dihedral angles of 72.5 (1) and 84.3 (1)° with the naphthalene system. In the crystal, mol­ecules are linked into...

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Detalles Bibliográficos
Autores principales: Hijikata, Daichi, Sasagawa, Kosuke, Yoshiwaka, Sayaka, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415034/
https://www.ncbi.nlm.nih.gov/pubmed/22905021
http://dx.doi.org/10.1107/S1600536812033521
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author Hijikata, Daichi
Sasagawa, Kosuke
Yoshiwaka, Sayaka
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Hijikata, Daichi
Sasagawa, Kosuke
Yoshiwaka, Sayaka
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Hijikata, Daichi
collection PubMed
description In the title compound, C(30)H(26)O(6)·C(3)H(6)O, the syn-oriented benzoyl groups are nearly parallel to each other; the dihedral angle between their benzene rings is 15.9 (1)°. They form dihedral angles of 72.5 (1) and 84.3 (1)° with the naphthalene system. In the crystal, mol­ecules are linked into a three-dimensional architecture by C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-34150342012-08-17 4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate Hijikata, Daichi Sasagawa, Kosuke Yoshiwaka, Sayaka Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(26)O(6)·C(3)H(6)O, the syn-oriented benzoyl groups are nearly parallel to each other; the dihedral angle between their benzene rings is 15.9 (1)°. They form dihedral angles of 72.5 (1) and 84.3 (1)° with the naphthalene system. In the crystal, mol­ecules are linked into a three-dimensional architecture by C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3415034/ /pubmed/22905021 http://dx.doi.org/10.1107/S1600536812033521 Text en © Hijikata et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hijikata, Daichi
Sasagawa, Kosuke
Yoshiwaka, Sayaka
Okamoto, Akiko
Yonezawa, Noriyuki
4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
title 4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
title_full 4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
title_fullStr 4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
title_full_unstemmed 4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
title_short 4-Hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
title_sort 4-hy­droxy­methyl-10-meth­oxy-17,22-dioxapenta­cyclo­[21.2.2.2(13,16).1(3,7).0(11,30)]triaconta-1(25),3,5,7(30),8,10,13,15,23,26,28-undeca­ene-2,12-dione acetone monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415034/
https://www.ncbi.nlm.nih.gov/pubmed/22905021
http://dx.doi.org/10.1107/S1600536812033521
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