Cargando…

Dimethyl­ammonium 5-carb­oxy-2-(1-oxo-1λ(5)-pyridin-2-yl)-1H-imidazole-4-car­box­yl­ate

In the title salt, C(2)H(8)N(+)·C(10)H(6)N(3)O(5) (−), the imidazole­carboxyl­ate anion is essentially planar [maximum deviation from the least-squares plane = 0.046 (5) Å], with a dihedral angle between the rings of 2.7 (2)°. This conformation is maintained by the presence of both intra­molecular c...

Descripción completa

Detalles Bibliográficos
Autores principales: Dai, Chuntao, Nie, Jianhua, Lin, Yuehua, Wang, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3415035/
https://www.ncbi.nlm.nih.gov/pubmed/22905022
http://dx.doi.org/10.1107/S1600536812033557
Descripción
Sumario:In the title salt, C(2)H(8)N(+)·C(10)H(6)N(3)O(5) (−), the imidazole­carboxyl­ate anion is essentially planar [maximum deviation from the least-squares plane = 0.046 (5) Å], with a dihedral angle between the rings of 2.7 (2)°. This conformation is maintained by the presence of both intra­molecular carb­oxy–carboxyl­ate O—H⋯O and imidazole–oxide N—H⋯O hydrogen bonds. Iin the crystal, cation–carboxyl­ate N—H⋯O and cation–imidazole N—H⋯N hydrogen bonds result in chains along the b axis.