Diaqua­tetra­bromidotin(IV) trihydrate

The title compound, [SnBr(4)(H(2)O)(2)]·3H(2)O, forms large colourless crystals in originally sealed samples of tin tetra­bromide. It constitutes the first structurally characterized hydrate of SnBr(4) and is isostructural with the corresponding ­hydrate of SnCl(4). It is composed of Sn(IV) atoms oc...

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Detalles Bibliográficos
Autores principales: Ye, Fei, Reuter, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435566/
https://www.ncbi.nlm.nih.gov/pubmed/22969439
http://dx.doi.org/10.1107/S1600536812036434
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author Ye, Fei
Reuter, Hans
author_facet Ye, Fei
Reuter, Hans
author_sort Ye, Fei
collection PubMed
description The title compound, [SnBr(4)(H(2)O)(2)]·3H(2)O, forms large colourless crystals in originally sealed samples of tin tetra­bromide. It constitutes the first structurally characterized hydrate of SnBr(4) and is isostructural with the corresponding ­hydrate of SnCl(4). It is composed of Sn(IV) atoms octa­hedrally coordinated by four Br atoms and two cis-related water mol­ecules. The octa­hedra exhibit site symmetry 2. They are arranged into columns along [001] via medium–strong O—H⋯O hydrogen bonds involving the two lattice water mol­ecules (one situated on a twofold rotation axis) while the chains are inter­connected via longer O—H⋯Br hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-34355662012-09-11 Diaqua­tetra­bromidotin(IV) trihydrate Ye, Fei Reuter, Hans Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, [SnBr(4)(H(2)O)(2)]·3H(2)O, forms large colourless crystals in originally sealed samples of tin tetra­bromide. It constitutes the first structurally characterized hydrate of SnBr(4) and is isostructural with the corresponding ­hydrate of SnCl(4). It is composed of Sn(IV) atoms octa­hedrally coordinated by four Br atoms and two cis-related water mol­ecules. The octa­hedra exhibit site symmetry 2. They are arranged into columns along [001] via medium–strong O—H⋯O hydrogen bonds involving the two lattice water mol­ecules (one situated on a twofold rotation axis) while the chains are inter­connected via longer O—H⋯Br hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2012-08-25 /pmc/articles/PMC3435566/ /pubmed/22969439 http://dx.doi.org/10.1107/S1600536812036434 Text en © Ye and Reuter 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ye, Fei
Reuter, Hans
Diaqua­tetra­bromidotin(IV) trihydrate
title Diaqua­tetra­bromidotin(IV) trihydrate
title_full Diaqua­tetra­bromidotin(IV) trihydrate
title_fullStr Diaqua­tetra­bromidotin(IV) trihydrate
title_full_unstemmed Diaqua­tetra­bromidotin(IV) trihydrate
title_short Diaqua­tetra­bromidotin(IV) trihydrate
title_sort diaqua­tetra­bromidotin(iv) trihydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435566/
https://www.ncbi.nlm.nih.gov/pubmed/22969439
http://dx.doi.org/10.1107/S1600536812036434
work_keys_str_mv AT yefei diaquatetrabromidotinivtrihydrate
AT reuterhans diaquatetrabromidotinivtrihydrate

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