[1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)

The reaction of 5-bromo­salicyl­aldehyde thio­semicarbazone with nickel acetate tetra­hydrate and pyridine yielded the title compound, [Ni(C(8)H(6)BrN(3)OS)(C(5)H(5)N)]. The Ni(II) atom is four-coordinated in a square-planar environment by one deprotonated dianionic thio­semicarbazone ligand, acting...

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Autores principales: Pederzolli, Fernanda Rosi Soares, Bresolin, Leandro, Beck, Johannes, Daniels, Jörg, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435568/
https://www.ncbi.nlm.nih.gov/pubmed/22969441
http://dx.doi.org/10.1107/S1600536812028917
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author Pederzolli, Fernanda Rosi Soares
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
author_facet Pederzolli, Fernanda Rosi Soares
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
author_sort Pederzolli, Fernanda Rosi Soares
collection PubMed
description The reaction of 5-bromo­salicyl­aldehyde thio­semicarbazone with nickel acetate tetra­hydrate and pyridine yielded the title compound, [Ni(C(8)H(6)BrN(3)OS)(C(5)H(5)N)]. The Ni(II) atom is four-coordinated in a square-planar environment by one deprotonated dianionic thio­semicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine mol­ecule. The complex mol­ecules are linked into dimers by pairs of centrosym­metrical N—H⋯N inter­actions. In addition, mol­ecules are connected through inter­molecular Br⋯Br inter­actions [3.545 (1) Å], forming chains along the b-axis direction.
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spelling pubmed-34355682012-09-11 [1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II) Pederzolli, Fernanda Rosi Soares Bresolin, Leandro Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 5-bromo­salicyl­aldehyde thio­semicarbazone with nickel acetate tetra­hydrate and pyridine yielded the title compound, [Ni(C(8)H(6)BrN(3)OS)(C(5)H(5)N)]. The Ni(II) atom is four-coordinated in a square-planar environment by one deprotonated dianionic thio­semicarbazone ligand, acting in a tridentate chelating mode through N, O and S atoms forming two metalla-rings, and by one pyridine mol­ecule. The complex mol­ecules are linked into dimers by pairs of centrosym­metrical N—H⋯N inter­actions. In addition, mol­ecules are connected through inter­molecular Br⋯Br inter­actions [3.545 (1) Å], forming chains along the b-axis direction. International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435568/ /pubmed/22969441 http://dx.doi.org/10.1107/S1600536812028917 Text en © Pederzolli et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pederzolli, Fernanda Rosi Soares
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
[1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)
title [1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)
title_full [1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)
title_fullStr [1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)
title_full_unstemmed [1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)
title_short [1-(5-Bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) O,N (1),S](pyridine-κN)nickel(II)
title_sort [1-(5-bromo-2-oxidobenzyl­idene)thio­semicarbazidato-κ(3) o,n (1),s](pyridine-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435568/
https://www.ncbi.nlm.nih.gov/pubmed/22969441
http://dx.doi.org/10.1107/S1600536812028917
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