Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]

In the title coordination polymer, [PbBr(C(6)H(5)N(2)O(2))(H(2)O)](n), the Pb(II) atom is coordinated by one pyrazine N atom, two bridging Br atoms, a water mol­ecule and three carboxyl­ate O atoms. Bridging by the two anions generates a layer structure parallel to (001); the layers are linked by O—...

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Detalles Bibliográficos
Autores principales: Yang, Pan, Liu, Yan, Li, Hua Yun, Ding, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435569/
https://www.ncbi.nlm.nih.gov/pubmed/22969442
http://dx.doi.org/10.1107/S1600536812033776
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author Yang, Pan
Liu, Yan
Li, Hua Yun
Ding, Bin
author_facet Yang, Pan
Liu, Yan
Li, Hua Yun
Ding, Bin
author_sort Yang, Pan
collection PubMed
description In the title coordination polymer, [PbBr(C(6)H(5)N(2)O(2))(H(2)O)](n), the Pb(II) atom is coordinated by one pyrazine N atom, two bridging Br atoms, a water mol­ecule and three carboxyl­ate O atoms. Bridging by the two anions generates a layer structure parallel to (001); the layers are linked by O—H⋯N and O—H⋯Br hydrogen bonds, forming a three-dimensional network. The lone pair is stereochemically active, resulting in a Ψ-dodeca­hedral coordination environment for Pb(II).
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spelling pubmed-34355692012-09-11 Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)] Yang, Pan Liu, Yan Li, Hua Yun Ding, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [PbBr(C(6)H(5)N(2)O(2))(H(2)O)](n), the Pb(II) atom is coordinated by one pyrazine N atom, two bridging Br atoms, a water mol­ecule and three carboxyl­ate O atoms. Bridging by the two anions generates a layer structure parallel to (001); the layers are linked by O—H⋯N and O—H⋯Br hydrogen bonds, forming a three-dimensional network. The lone pair is stereochemically active, resulting in a Ψ-dodeca­hedral coordination environment for Pb(II). International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435569/ /pubmed/22969442 http://dx.doi.org/10.1107/S1600536812033776 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Pan
Liu, Yan
Li, Hua Yun
Ding, Bin
Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]
title Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]
title_full Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]
title_fullStr Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]
title_full_unstemmed Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]
title_short Poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2):O (2),O (2′))lead(II)]
title_sort poly[aqua-μ-bromido-(μ(2)-5-methyl­pyrazine-2-carboxyl­ato-κ(4) n (1),o (2):o (2),o (2′))lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435569/
https://www.ncbi.nlm.nih.gov/pubmed/22969442
http://dx.doi.org/10.1107/S1600536812033776
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AT dingbin polyaquambromidom25methylpyrazine2carboxylatok4n1o2o2o2leadii

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