catena-Poly[[(1,3-dimethyl­imidazolin-2-one-κN)(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxyl­ato-κ(2) O (2):O (5)]

The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethyl­imidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxyl­ate groups of the furan-2,5-dicarboxyl­ate liga...

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Detalles Bibliográficos
Autores principales: Li, Ya-Feng, Xu, Yue, Qin, Xiao-Lin, Yuan, Yong-Peng, Gao, Wen-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435570/
https://www.ncbi.nlm.nih.gov/pubmed/22969443
http://dx.doi.org/10.1107/S160053681203111X
Descripción
Sumario:The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethyl­imidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxyl­ate groups of the furan-2,5-dicarboxyl­ate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordination. The dihedral angles of the 1,10-phenanthroline ligand with respect to the furan rings of the carboxyl­ate anions that are connected to the metal atom are 62.18 (11) and 88.27 (12)°.

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