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catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)]
The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethylimidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxylate groups of the furan-2,5-dicarboxylate liga...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435570/ https://www.ncbi.nlm.nih.gov/pubmed/22969443 http://dx.doi.org/10.1107/S160053681203111X |
| _version_ | 1782242541965410304 |
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| author | Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan |
| author_facet | Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan |
| author_sort | Li, Ya-Feng |
| collection | PubMed |
| description | The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethylimidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxylate groups of the furan-2,5-dicarboxylate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordination. The dihedral angles of the 1,10-phenanthroline ligand with respect to the furan rings of the carboxylate anions that are connected to the metal atom are 62.18 (11) and 88.27 (12)°. |
| format | Online Article Text |
| id | pubmed-3435570 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34355702012-09-11 catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)] Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethylimidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxylate groups of the furan-2,5-dicarboxylate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordination. The dihedral angles of the 1,10-phenanthroline ligand with respect to the furan rings of the carboxylate anions that are connected to the metal atom are 62.18 (11) and 88.27 (12)°. International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435570/ /pubmed/22969443 http://dx.doi.org/10.1107/S160053681203111X Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2) O (2):O (5)] |
| title |
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] |
| title_full |
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] |
| title_fullStr |
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] |
| title_full_unstemmed |
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] |
| title_short |
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ(2)
O
(2):O
(5)] |
| title_sort | catena-poly[[(1,3-dimethylimidazolin-2-one-κn)(1,10-phenanthroline-κ(2)
n,n′)copper(ii)]-μ-furan-2,5-dicarboxylato-κ(2)
o
(2):o
(5)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435570/ https://www.ncbi.nlm.nih.gov/pubmed/22969443 http://dx.doi.org/10.1107/S160053681203111X |
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