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catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]

In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate l...

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Detalles Bibliográficos
Autores principales: Bugenhagen, Bernhard E. C., Prosenc, Marc H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435572/
https://www.ncbi.nlm.nih.gov/pubmed/22969445
http://dx.doi.org/10.1107/S1600536812033405
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author Bugenhagen, Bernhard E. C.
Prosenc, Marc H.
author_facet Bugenhagen, Bernhard E. C.
Prosenc, Marc H.
author_sort Bugenhagen, Bernhard E. C.
collection PubMed
description In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate ligands as in the crystal structure of copper acetate monohydrate. The fifth, apically coordinating ligand links two of the dicopper tetra­acetate paddlewheel-units together, thus building a linear coordination polymer which extends along [10-1]. Each apical acetate ligand is linked by an N—H⋯O hydrogen bond to a triethyl­ammonium cation. Weak C—H⋯O hydrogen bonding interactions also occur.
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spelling pubmed-34355722012-09-11 catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate] Bugenhagen, Bernhard E. C. Prosenc, Marc H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate ligands as in the crystal structure of copper acetate monohydrate. The fifth, apically coordinating ligand links two of the dicopper tetra­acetate paddlewheel-units together, thus building a linear coordination polymer which extends along [10-1]. Each apical acetate ligand is linked by an N—H⋯O hydrogen bond to a triethyl­ammonium cation. Weak C—H⋯O hydrogen bonding interactions also occur. International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435572/ /pubmed/22969445 http://dx.doi.org/10.1107/S1600536812033405 Text en © Bugenhagen and Prosenc 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bugenhagen, Bernhard E. C.
Prosenc, Marc H.
catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]
title catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]
title_full catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]
title_fullStr catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]
title_full_unstemmed catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]
title_short catena-Poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetra­hydro­furan monosolvate]
title_sort catena-poly[triethyl­ammonium [[tetra-μ-acetato-κ(8) o:o′-dicuprate(ii)]-μ-acetato-κ(2) o:o′] tetra­hydro­furan monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435572/
https://www.ncbi.nlm.nih.gov/pubmed/22969445
http://dx.doi.org/10.1107/S1600536812033405
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