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catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetrahydrofuran monosolvate]
In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate l...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435572/ https://www.ncbi.nlm.nih.gov/pubmed/22969445 http://dx.doi.org/10.1107/S1600536812033405 |
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author | Bugenhagen, Bernhard E. C. Prosenc, Marc H. |
author_facet | Bugenhagen, Bernhard E. C. Prosenc, Marc H. |
author_sort | Bugenhagen, Bernhard E. C. |
collection | PubMed |
description | In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate ligands as in the crystal structure of copper acetate monohydrate. The fifth, apically coordinating ligand links two of the dicopper tetraacetate paddlewheel-units together, thus building a linear coordination polymer which extends along [10-1]. Each apical acetate ligand is linked by an N—H⋯O hydrogen bond to a triethylammonium cation. Weak C—H⋯O hydrogen bonding interactions also occur. |
format | Online Article Text |
id | pubmed-3435572 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34355722012-09-11 catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetrahydrofuran monosolvate] Bugenhagen, Bernhard E. C. Prosenc, Marc H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[(C(2)H(5))(3)NH][Cu(2)(CH(3)COO)(5)]·C(4)H(8)O}(n), the two different Cu(II) atoms are coordinated in a pseudo-square-pyramidal environment by five O atoms from the acetate ligands. Neighbouring pairs of Cu(II) atoms are linked by four basally coordinating bridging acetate ligands as in the crystal structure of copper acetate monohydrate. The fifth, apically coordinating ligand links two of the dicopper tetraacetate paddlewheel-units together, thus building a linear coordination polymer which extends along [10-1]. Each apical acetate ligand is linked by an N—H⋯O hydrogen bond to a triethylammonium cation. Weak C—H⋯O hydrogen bonding interactions also occur. International Union of Crystallography 2012-08-01 /pmc/articles/PMC3435572/ /pubmed/22969445 http://dx.doi.org/10.1107/S1600536812033405 Text en © Bugenhagen and Prosenc 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bugenhagen, Bernhard E. C. Prosenc, Marc H. catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8) O:O′-dicuprate(II)]-μ-acetato-κ(2) O:O′] tetrahydrofuran monosolvate] |
title |
catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)]-μ-acetato-κ(2)
O:O′] tetrahydrofuran monosolvate] |
title_full |
catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)]-μ-acetato-κ(2)
O:O′] tetrahydrofuran monosolvate] |
title_fullStr |
catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)]-μ-acetato-κ(2)
O:O′] tetrahydrofuran monosolvate] |
title_full_unstemmed |
catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)]-μ-acetato-κ(2)
O:O′] tetrahydrofuran monosolvate] |
title_short |
catena-Poly[triethylammonium [[tetra-μ-acetato-κ(8)
O:O′-dicuprate(II)]-μ-acetato-κ(2)
O:O′] tetrahydrofuran monosolvate] |
title_sort | catena-poly[triethylammonium [[tetra-μ-acetato-κ(8)
o:o′-dicuprate(ii)]-μ-acetato-κ(2)
o:o′] tetrahydrofuran monosolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435572/ https://www.ncbi.nlm.nih.gov/pubmed/22969445 http://dx.doi.org/10.1107/S1600536812033405 |
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