Dibromido(6,6′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cadmium

In the title compound, [CdBr(2)(C(12)H(12)N(2))], the Cd(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, C—H⋯Br hydrogen bonds and π–π stacking inter­actions between the pyridine r...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435573/
https://www.ncbi.nlm.nih.gov/pubmed/22969446
http://dx.doi.org/10.1107/S1600536812033648
Descripción
Sumario:In the title compound, [CdBr(2)(C(12)H(12)N(2))], the Cd(II) atom is four-coordinated in a distorted tetra­hedral geometry by two N atoms from a 6,6′-dimethyl-2,2′-bipyridine ligand and two terminal Br atoms. In the crystal, C—H⋯Br hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid–centroid distance = 3.763 (5) Å] are present.

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