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(Di-2-pyridyl­amine-κ(2) N (2),N (2′))diiodidopalladium(II)

The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine r...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435574/
https://www.ncbi.nlm.nih.gov/pubmed/22969447
http://dx.doi.org/10.1107/S1600536812033946
Descripción
Sumario:The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl­amine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 51.2 (2)°. In the crystal, pairs of complex mol­ecules are assembled through inter­molecular N—H⋯I hydrogen bonds into dimeric species. The complexes are stacked in columns along the b axis and display several inter­molecular π–π inter­actions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.957 (3) Å.