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(Di-2-pyridylamine-κ(2) N (2),N (2′))diiodidopalladium(II)
The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine r...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435574/ https://www.ncbi.nlm.nih.gov/pubmed/22969447 http://dx.doi.org/10.1107/S1600536812033946 |
Sumario: | The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 51.2 (2)°. In the crystal, pairs of complex molecules are assembled through intermolecular N—H⋯I hydrogen bonds into dimeric species. The complexes are stacked in columns along the b axis and display several intermolecular π–π interactions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.957 (3) Å. |
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