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(Di-2-pyridylamine-κ(2) N (2),N (2′))diiodidopalladium(II)
The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine r...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435574/ https://www.ncbi.nlm.nih.gov/pubmed/22969447 http://dx.doi.org/10.1107/S1600536812033946 |
| _version_ | 1782242542911225856 |
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| author | Ha, Kwang |
| author_facet | Ha, Kwang |
| author_sort | Ha, Kwang |
| collection | PubMed |
| description | The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 51.2 (2)°. In the crystal, pairs of complex molecules are assembled through intermolecular N—H⋯I hydrogen bonds into dimeric species. The complexes are stacked in columns along the b axis and display several intermolecular π–π interactions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.957 (3) Å. |
| format | Online Article Text |
| id | pubmed-3435574 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34355742012-09-11 (Di-2-pyridylamine-κ(2) N (2),N (2′))diiodidopalladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and two I(−) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 51.2 (2)°. In the crystal, pairs of complex molecules are assembled through intermolecular N—H⋯I hydrogen bonds into dimeric species. The complexes are stacked in columns along the b axis and display several intermolecular π–π interactions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.957 (3) Å. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435574/ /pubmed/22969447 http://dx.doi.org/10.1107/S1600536812033946 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ha, Kwang (Di-2-pyridylamine-κ(2) N (2),N (2′))diiodidopalladium(II) |
| title | (Di-2-pyridylamine-κ(2)
N
(2),N
(2′))diiodidopalladium(II) |
| title_full | (Di-2-pyridylamine-κ(2)
N
(2),N
(2′))diiodidopalladium(II) |
| title_fullStr | (Di-2-pyridylamine-κ(2)
N
(2),N
(2′))diiodidopalladium(II) |
| title_full_unstemmed | (Di-2-pyridylamine-κ(2)
N
(2),N
(2′))diiodidopalladium(II) |
| title_short | (Di-2-pyridylamine-κ(2)
N
(2),N
(2′))diiodidopalladium(II) |
| title_sort | (di-2-pyridylamine-κ(2)
n
(2),n
(2′))diiodidopalladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435574/ https://www.ncbi.nlm.nih.gov/pubmed/22969447 http://dx.doi.org/10.1107/S1600536812033946 |
| work_keys_str_mv | AT hakwang di2pyridylaminek2n2n2diiodidopalladiumii |