Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)

The Pd(II) atom of the title salt, [Pd(C(10)H(9)N(3))(2)](NCS)(2), lies on a center of inversion and exists in a square-planar environment defined by the four pyridine N atoms derived from the two chelating di-2-pyridyl­amine (dpa) ligands. The chelate ring displays a boat conformation with a dihedr...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435575/
https://www.ncbi.nlm.nih.gov/pubmed/22969448
http://dx.doi.org/10.1107/S1600536812033958
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
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description The Pd(II) atom of the title salt, [Pd(C(10)H(9)N(3))(2)](NCS)(2), lies on a center of inversion and exists in a square-planar environment defined by the four pyridine N atoms derived from the two chelating di-2-pyridyl­amine (dpa) ligands. The chelate ring displays a boat conformation with a dihedral angle between the pyridine rings of 43.0 (1)°. Adjacent thio­cyanate ions are linked to the cations by N—H⋯N hydrogen bonds.
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spelling pubmed-34355752012-09-11 Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) atom of the title salt, [Pd(C(10)H(9)N(3))(2)](NCS)(2), lies on a center of inversion and exists in a square-planar environment defined by the four pyridine N atoms derived from the two chelating di-2-pyridyl­amine (dpa) ligands. The chelate ring displays a boat conformation with a dihedral angle between the pyridine rings of 43.0 (1)°. Adjacent thio­cyanate ions are linked to the cations by N—H⋯N hydrogen bonds. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435575/ /pubmed/22969448 http://dx.doi.org/10.1107/S1600536812033958 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)
title Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)
title_full Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)
title_fullStr Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)
title_full_unstemmed Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)
title_short Bis(di-2-pyridyl­amine-κ(2) N (2),N (2′))palladium(II) bis­(thio­cyanate)
title_sort bis(di-2-pyridyl­amine-κ(2) n (2),n (2′))palladium(ii) bis­(thio­cyanate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435575/
https://www.ncbi.nlm.nih.gov/pubmed/22969448
http://dx.doi.org/10.1107/S1600536812033958
work_keys_str_mv AT hakwang bisdi2pyridylaminek2n2n2palladiumiibisthiocyanate

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