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Poly[[diaquabis(μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′))bis(μ(3)-5-oxidopyridin-1-ium-3-carboxylato-κ(3) O (3):O (3′):O (5))diholmium(III)] dihydrate]
In the title compound, {[Ho(2)(C(6)H(4)NO(3))(2)(C(2)O(4))(2)(H(2)O)(2)]·2H(2)O}(n), the Ho(III) atom is coordinated by three O atoms from three 5-hydroxynicotinate ligands, four O atoms from two oxalate ligands, each lying on an inversion center, and one water molecule in a distorted square-anti...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435576/ https://www.ncbi.nlm.nih.gov/pubmed/22969449 http://dx.doi.org/10.1107/S1600536812032916 |
Sumario: | In the title compound, {[Ho(2)(C(6)H(4)NO(3))(2)(C(2)O(4))(2)(H(2)O)(2)]·2H(2)O}(n), the Ho(III) atom is coordinated by three O atoms from three 5-hydroxynicotinate ligands, four O atoms from two oxalate ligands, each lying on an inversion center, and one water molecule in a distorted square-antiprismatic geometry. The 5-hydroxynicotinate ligand is protonated at the N atom and deprotonated at the hydroxy group. The Ho(III) atoms are bridged by the carboxylate and phenolate O atoms, forming a three-dimensional framework. N—H⋯O and O—H⋯O hydrogen bonds, as well as π–π interactions between the pyridine rings [centroid–centroid distance = 3.794 (2) Å], are observed. |
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