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catena-Poly[[[(1,10-phenanthroline-κ(2) N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4) O (1):O (1′)-μ-nitrato-κ(3) O,O′:O] bis(1,10-phenanthroline)]
The title complex, [Pr(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))]·2C(12)H(8)N(2), has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The Pr(III) centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one che...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435577/ https://www.ncbi.nlm.nih.gov/pubmed/22969450 http://dx.doi.org/10.1107/S1600536812029911 |
| _version_ | 1782242543613771776 |
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| author | Wang, Panfeng Xu, Dingding Wang, Xinqing |
| author_facet | Wang, Panfeng Xu, Dingding Wang, Xinqing |
| author_sort | Wang, Panfeng |
| collection | PubMed |
| description | The title complex, [Pr(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))]·2C(12)H(8)N(2), has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The Pr(III) centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxylate O atoms from four 4-hydroxybenzoate anions and three O atoms from two nitrate anions. The 4-hydroxybenzoate and nitrate anions function as μ(2)-bridging ligands and link the Pr(III) ions into a one-dimensional chain structure along the c axis. Intermolecular O—H⋯N hydrogen bonds are observed between the 4-hydroxybenzoate anions and the uncoordinated 1,10-phenanthroline molecules. |
| format | Online Article Text |
| id | pubmed-3435577 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34355772012-09-11 catena-Poly[[[(1,10-phenanthroline-κ(2) N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4) O (1):O (1′)-μ-nitrato-κ(3) O,O′:O] bis(1,10-phenanthroline)] Wang, Panfeng Xu, Dingding Wang, Xinqing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Pr(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))]·2C(12)H(8)N(2), has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline molecules in the lattice. The Pr(III) centre has a monocapped square-antiprismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxylate O atoms from four 4-hydroxybenzoate anions and three O atoms from two nitrate anions. The 4-hydroxybenzoate and nitrate anions function as μ(2)-bridging ligands and link the Pr(III) ions into a one-dimensional chain structure along the c axis. Intermolecular O—H⋯N hydrogen bonds are observed between the 4-hydroxybenzoate anions and the uncoordinated 1,10-phenanthroline molecules. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435577/ /pubmed/22969450 http://dx.doi.org/10.1107/S1600536812029911 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Panfeng Xu, Dingding Wang, Xinqing catena-Poly[[[(1,10-phenanthroline-κ(2) N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4) O (1):O (1′)-μ-nitrato-κ(3) O,O′:O] bis(1,10-phenanthroline)] |
| title |
catena-Poly[[[(1,10-phenanthroline-κ(2)
N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4)
O
(1):O
(1′)-μ-nitrato-κ(3)
O,O′:O] bis(1,10-phenanthroline)] |
| title_full |
catena-Poly[[[(1,10-phenanthroline-κ(2)
N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4)
O
(1):O
(1′)-μ-nitrato-κ(3)
O,O′:O] bis(1,10-phenanthroline)] |
| title_fullStr |
catena-Poly[[[(1,10-phenanthroline-κ(2)
N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4)
O
(1):O
(1′)-μ-nitrato-κ(3)
O,O′:O] bis(1,10-phenanthroline)] |
| title_full_unstemmed |
catena-Poly[[[(1,10-phenanthroline-κ(2)
N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4)
O
(1):O
(1′)-μ-nitrato-κ(3)
O,O′:O] bis(1,10-phenanthroline)] |
| title_short |
catena-Poly[[[(1,10-phenanthroline-κ(2)
N,N′)praseodymium(III)]-di-μ-4-hydroxybenzoato-κ(4)
O
(1):O
(1′)-μ-nitrato-κ(3)
O,O′:O] bis(1,10-phenanthroline)] |
| title_sort | catena-poly[[[(1,10-phenanthroline-κ(2)
n,n′)praseodymium(iii)]-di-μ-4-hydroxybenzoato-κ(4)
o
(1):o
(1′)-μ-nitrato-κ(3)
o,o′:o] bis(1,10-phenanthroline)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435577/ https://www.ncbi.nlm.nih.gov/pubmed/22969450 http://dx.doi.org/10.1107/S1600536812029911 |
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