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Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium

In the centrosymmetric title compound, [Cd(C(7)H(4)NO(4))(2)(C(3)H(4)N(2))(2)(H(2)O)(2)], the Cd(II) atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octa­hedral geometry. The inter­nal cohesion of the mol­ecule is enhanced by an intra­molecular O—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Mao, Yan-Li, Yu, Xiao-Ke, Lin, Jian-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435578/
https://www.ncbi.nlm.nih.gov/pubmed/22969451
http://dx.doi.org/10.1107/S1600536812033739
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author Mao, Yan-Li
Yu, Xiao-Ke
Lin, Jian-Li
author_facet Mao, Yan-Li
Yu, Xiao-Ke
Lin, Jian-Li
author_sort Mao, Yan-Li
collection PubMed
description In the centrosymmetric title compound, [Cd(C(7)H(4)NO(4))(2)(C(3)H(4)N(2))(2)(H(2)O)(2)], the Cd(II) atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octa­hedral geometry. The inter­nal cohesion of the mol­ecule is enhanced by an intra­molecular O—H⋯O hydrogen bond. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and π–π contacts [centroid–centroid distance = 3.6549 (2) Å] define two-dimensional networks parallel to (001), which are further connected by weaker C—H⋯O inter­actions into a weakly connected three-dimensional supra­molecular framework.
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spelling pubmed-34355782012-09-11 Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium Mao, Yan-Li Yu, Xiao-Ke Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Cd(C(7)H(4)NO(4))(2)(C(3)H(4)N(2))(2)(H(2)O)(2)], the Cd(II) atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octa­hedral geometry. The inter­nal cohesion of the mol­ecule is enhanced by an intra­molecular O—H⋯O hydrogen bond. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and π–π contacts [centroid–centroid distance = 3.6549 (2) Å] define two-dimensional networks parallel to (001), which are further connected by weaker C—H⋯O inter­actions into a weakly connected three-dimensional supra­molecular framework. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435578/ /pubmed/22969451 http://dx.doi.org/10.1107/S1600536812033739 Text en © Mao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mao, Yan-Li
Yu, Xiao-Ke
Lin, Jian-Li
Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium
title Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium
title_full Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium
title_fullStr Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium
title_full_unstemmed Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium
title_short Diaqua­bis­(1H-imidazole-κN (3))bis­(4-nitro­benzoato-κO (1))cadmium
title_sort diaqua­bis­(1h-imidazole-κn (3))bis­(4-nitro­benzoato-κo (1))cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435578/
https://www.ncbi.nlm.nih.gov/pubmed/22969451
http://dx.doi.org/10.1107/S1600536812033739
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