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Diaquabis(1H-imidazole-κN (3))bis(4-nitrobenzoato-κO (1))cadmium
In the centrosymmetric title compound, [Cd(C(7)H(4)NO(4))(2)(C(3)H(4)N(2))(2)(H(2)O)(2)], the Cd(II) atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H⋯O hydrog...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435578/ https://www.ncbi.nlm.nih.gov/pubmed/22969451 http://dx.doi.org/10.1107/S1600536812033739 |
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author | Mao, Yan-Li Yu, Xiao-Ke Lin, Jian-Li |
author_facet | Mao, Yan-Li Yu, Xiao-Ke Lin, Jian-Li |
author_sort | Mao, Yan-Li |
collection | PubMed |
description | In the centrosymmetric title compound, [Cd(C(7)H(4)NO(4))(2)(C(3)H(4)N(2))(2)(H(2)O)(2)], the Cd(II) atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H⋯O hydrogen bond. Intermolecular O—H⋯O and C—H⋯O hydrogen bonds and π–π contacts [centroid–centroid distance = 3.6549 (2) Å] define two-dimensional networks parallel to (001), which are further connected by weaker C—H⋯O interactions into a weakly connected three-dimensional supramolecular framework. |
format | Online Article Text |
id | pubmed-3435578 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34355782012-09-11 Diaquabis(1H-imidazole-κN (3))bis(4-nitrobenzoato-κO (1))cadmium Mao, Yan-Li Yu, Xiao-Ke Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Cd(C(7)H(4)NO(4))(2)(C(3)H(4)N(2))(2)(H(2)O)(2)], the Cd(II) atom, located on an inversion center, is coordinated by two N atoms and four O atoms in an octahedral geometry. The internal cohesion of the molecule is enhanced by an intramolecular O—H⋯O hydrogen bond. Intermolecular O—H⋯O and C—H⋯O hydrogen bonds and π–π contacts [centroid–centroid distance = 3.6549 (2) Å] define two-dimensional networks parallel to (001), which are further connected by weaker C—H⋯O interactions into a weakly connected three-dimensional supramolecular framework. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435578/ /pubmed/22969451 http://dx.doi.org/10.1107/S1600536812033739 Text en © Mao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mao, Yan-Li Yu, Xiao-Ke Lin, Jian-Li Diaquabis(1H-imidazole-κN (3))bis(4-nitrobenzoato-κO (1))cadmium |
title | Diaquabis(1H-imidazole-κN
(3))bis(4-nitrobenzoato-κO
(1))cadmium |
title_full | Diaquabis(1H-imidazole-κN
(3))bis(4-nitrobenzoato-κO
(1))cadmium |
title_fullStr | Diaquabis(1H-imidazole-κN
(3))bis(4-nitrobenzoato-κO
(1))cadmium |
title_full_unstemmed | Diaquabis(1H-imidazole-κN
(3))bis(4-nitrobenzoato-κO
(1))cadmium |
title_short | Diaquabis(1H-imidazole-κN
(3))bis(4-nitrobenzoato-κO
(1))cadmium |
title_sort | diaquabis(1h-imidazole-κn
(3))bis(4-nitrobenzoato-κo
(1))cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435578/ https://www.ncbi.nlm.nih.gov/pubmed/22969451 http://dx.doi.org/10.1107/S1600536812033739 |
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