Dichloridobis(4-fluoro­aniline-κN)zinc

In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra­hedral geometry, being coordinated by the N atoms of two 4-fluoro­aniline mol­ecules and the two Cl(−) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89....

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Detalles Bibliográficos
Autores principales: Subashini, Ashokkumar, Ramamurthi, Kandasamy, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435581/
https://www.ncbi.nlm.nih.gov/pubmed/22969454
http://dx.doi.org/10.1107/S1600536812033922
Descripción
Sumario:In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra­hedral geometry, being coordinated by the N atoms of two 4-fluoro­aniline mol­ecules and the two Cl(−) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°. In the crystal, mol­ecules are linked via pairs of N—H⋯Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to the ab plane. The title compound crystallizes in the space group Pca2(1) and exhibits weak second harmonic generation (SHG) properties.

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