Dichloridobis(4-fluoro­aniline-κN)zinc

In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra­hedral geometry, being coordinated by the N atoms of two 4-fluoro­aniline mol­ecules and the two Cl(−) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89....

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Autores principales: Subashini, Ashokkumar, Ramamurthi, Kandasamy, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435581/
https://www.ncbi.nlm.nih.gov/pubmed/22969454
http://dx.doi.org/10.1107/S1600536812033922
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author Subashini, Ashokkumar
Ramamurthi, Kandasamy
Stoeckli-Evans, Helen
author_facet Subashini, Ashokkumar
Ramamurthi, Kandasamy
Stoeckli-Evans, Helen
author_sort Subashini, Ashokkumar
collection PubMed
description In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra­hedral geometry, being coordinated by the N atoms of two 4-fluoro­aniline mol­ecules and the two Cl(−) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°. In the crystal, mol­ecules are linked via pairs of N—H⋯Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to the ab plane. The title compound crystallizes in the space group Pca2(1) and exhibits weak second harmonic generation (SHG) properties.
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spelling pubmed-34355812012-09-11 Dichloridobis(4-fluoro­aniline-κN)zinc Subashini, Ashokkumar Ramamurthi, Kandasamy Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra­hedral geometry, being coordinated by the N atoms of two 4-fluoro­aniline mol­ecules and the two Cl(−) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°. In the crystal, mol­ecules are linked via pairs of N—H⋯Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to the ab plane. The title compound crystallizes in the space group Pca2(1) and exhibits weak second harmonic generation (SHG) properties. International Union of Crystallography 2012-08-04 /pmc/articles/PMC3435581/ /pubmed/22969454 http://dx.doi.org/10.1107/S1600536812033922 Text en © Subashini et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Subashini, Ashokkumar
Ramamurthi, Kandasamy
Stoeckli-Evans, Helen
Dichloridobis(4-fluoro­aniline-κN)zinc
title Dichloridobis(4-fluoro­aniline-κN)zinc
title_full Dichloridobis(4-fluoro­aniline-κN)zinc
title_fullStr Dichloridobis(4-fluoro­aniline-κN)zinc
title_full_unstemmed Dichloridobis(4-fluoro­aniline-κN)zinc
title_short Dichloridobis(4-fluoro­aniline-κN)zinc
title_sort dichloridobis(4-fluoro­aniline-κn)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435581/
https://www.ncbi.nlm.nih.gov/pubmed/22969454
http://dx.doi.org/10.1107/S1600536812033922
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