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(Ethylenediamine-κ(2) N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN (1)]cobalt(III) nitrate monohydrate
In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435583/ https://www.ncbi.nlm.nih.gov/pubmed/22969456 http://dx.doi.org/10.1107/S1600536812032692 |
Sumario: | In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure. |
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