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(Ethylenediamine-κ(2) N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN (1)]cobalt(III) nitrate monohydrate
In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435583/ https://www.ncbi.nlm.nih.gov/pubmed/22969456 http://dx.doi.org/10.1107/S1600536812032692 |
| _version_ | 1782242545017815040 |
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| author | Feng, Xiu-Ling Zhang, Yu-Ping |
| author_facet | Feng, Xiu-Ling Zhang, Yu-Ping |
| author_sort | Feng, Xiu-Ling |
| collection | PubMed |
| description | In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure. |
| format | Online Article Text |
| id | pubmed-3435583 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34355832012-09-11 (Ethylenediamine-κ(2) N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN (1)]cobalt(III) nitrate monohydrate Feng, Xiu-Ling Zhang, Yu-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(6)N(3))(2)(C(2)H(8)N(2))]NO(3)·H(2)O, the Co(III) ion is coordinated by four N atoms from two 2-(pyridin-2-yl)-1,3-imidazol-1-ide ligands and two N atoms of ethylenediamine in a distorted octahedral geometry. In the crystal, classical N—H⋯N(O) and O—H⋯N(O) hydrogen bonds connect all the isolated components together to yield a three-dimensional structure. International Union of Crystallography 2012-08-08 /pmc/articles/PMC3435583/ /pubmed/22969456 http://dx.doi.org/10.1107/S1600536812032692 Text en © Feng and Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Feng, Xiu-Ling Zhang, Yu-Ping (Ethylenediamine-κ(2) N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN (1)]cobalt(III) nitrate monohydrate |
| title | (Ethylenediamine-κ(2)
N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN
(1)]cobalt(III) nitrate monohydrate |
| title_full | (Ethylenediamine-κ(2)
N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN
(1)]cobalt(III) nitrate monohydrate |
| title_fullStr | (Ethylenediamine-κ(2)
N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN
(1)]cobalt(III) nitrate monohydrate |
| title_full_unstemmed | (Ethylenediamine-κ(2)
N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN
(1)]cobalt(III) nitrate monohydrate |
| title_short | (Ethylenediamine-κ(2)
N,N)bis[2-(pyridin-2-yl-κN)-1,3-imidazol-1-ido-κN
(1)]cobalt(III) nitrate monohydrate |
| title_sort | (ethylenediamine-κ(2)
n,n)bis[2-(pyridin-2-yl-κn)-1,3-imidazol-1-ido-κn
(1)]cobalt(iii) nitrate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435583/ https://www.ncbi.nlm.nih.gov/pubmed/22969456 http://dx.doi.org/10.1107/S1600536812032692 |
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