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Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)

In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar mol­ecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetra­coordinated, displaying a slightly distorted square-planar geometry. The main deviation from the idea...

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Detalles Bibliográficos
Autores principales: Petrusenko, Svitlana R., Belozub, Yaroslava I., Kokozay, Volodymyr N., Omelchenko, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435589/
https://www.ncbi.nlm.nih.gov/pubmed/22969462
http://dx.doi.org/10.1107/S1600536812032187
Descripción
Sumario:In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar mol­ecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetra­coordinated, displaying a slightly distorted square-planar geometry. The main deviation from the ideal geometry is seen in the differences in the Cu—O [1.8833 (10) Å] and Cu—N [1.9405 (13) Å] bond lengths, while angular deviations are less than 3°. Intra­molecular O—H⋯O and inter­molecular Csp(2)—H⋯O hydrogen bonds form S(5) and R (2) (2)(8) ring motifs, respectively. The latter inter­action results in chains of mol­ecules along [100].