Cargando…

Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)

In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar mol­ecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetra­coordinated, displaying a slightly distorted square-planar geometry. The main deviation from the idea...

Descripción completa

Detalles Bibliográficos
Autores principales: Petrusenko, Svitlana R., Belozub, Yaroslava I., Kokozay, Volodymyr N., Omelchenko, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435589/
https://www.ncbi.nlm.nih.gov/pubmed/22969462
http://dx.doi.org/10.1107/S1600536812032187
_version_ 1782242546461704192
author Petrusenko, Svitlana R.
Belozub, Yaroslava I.
Kokozay, Volodymyr N.
Omelchenko, Irina V.
author_facet Petrusenko, Svitlana R.
Belozub, Yaroslava I.
Kokozay, Volodymyr N.
Omelchenko, Irina V.
author_sort Petrusenko, Svitlana R.
collection PubMed
description In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar mol­ecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetra­coordinated, displaying a slightly distorted square-planar geometry. The main deviation from the ideal geometry is seen in the differences in the Cu—O [1.8833 (10) Å] and Cu—N [1.9405 (13) Å] bond lengths, while angular deviations are less than 3°. Intra­molecular O—H⋯O and inter­molecular Csp(2)—H⋯O hydrogen bonds form S(5) and R (2) (2)(8) ring motifs, respectively. The latter inter­action results in chains of mol­ecules along [100].
format Online
Article
Text
id pubmed-3435589
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34355892012-09-11 Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II) Petrusenko, Svitlana R. Belozub, Yaroslava I. Kokozay, Volodymyr N. Omelchenko, Irina V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar mol­ecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetra­coordinated, displaying a slightly distorted square-planar geometry. The main deviation from the ideal geometry is seen in the differences in the Cu—O [1.8833 (10) Å] and Cu—N [1.9405 (13) Å] bond lengths, while angular deviations are less than 3°. Intra­molecular O—H⋯O and inter­molecular Csp(2)—H⋯O hydrogen bonds form S(5) and R (2) (2)(8) ring motifs, respectively. The latter inter­action results in chains of mol­ecules along [100]. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435589/ /pubmed/22969462 http://dx.doi.org/10.1107/S1600536812032187 Text en © Petrusenko et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Petrusenko, Svitlana R.
Belozub, Yaroslava I.
Kokozay, Volodymyr N.
Omelchenko, Irina V.
Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)
title Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)
title_full Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)
title_fullStr Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)
title_full_unstemmed Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)
title_short Bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) N,O (1))copper(II)
title_sort bis(2-hy­droxy­imino­methyl-6-meth­oxy­phenolato-κ(2) n,o (1))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435589/
https://www.ncbi.nlm.nih.gov/pubmed/22969462
http://dx.doi.org/10.1107/S1600536812032187
work_keys_str_mv AT petrusenkosvitlanar bis2hydroxyiminomethyl6methoxyphenolatok2no1copperii
AT belozubyaroslavai bis2hydroxyiminomethyl6methoxyphenolatok2no1copperii
AT kokozayvolodymyrn bis2hydroxyiminomethyl6methoxyphenolatok2no1copperii
AT omelchenkoirinav bis2hydroxyiminomethyl6methoxyphenolatok2no1copperii