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Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2) N,O (1))copper(II)
In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar molecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetracoordinated, displaying a slightly distorted square-planar geometry. The main deviation from the idea...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435589/ https://www.ncbi.nlm.nih.gov/pubmed/22969462 http://dx.doi.org/10.1107/S1600536812032187 |
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author | Petrusenko, Svitlana R. Belozub, Yaroslava I. Kokozay, Volodymyr N. Omelchenko, Irina V. |
author_facet | Petrusenko, Svitlana R. Belozub, Yaroslava I. Kokozay, Volodymyr N. Omelchenko, Irina V. |
author_sort | Petrusenko, Svitlana R. |
collection | PubMed |
description | In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar molecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetracoordinated, displaying a slightly distorted square-planar geometry. The main deviation from the ideal geometry is seen in the differences in the Cu—O [1.8833 (10) Å] and Cu—N [1.9405 (13) Å] bond lengths, while angular deviations are less than 3°. Intramolecular O—H⋯O and intermolecular Csp(2)—H⋯O hydrogen bonds form S(5) and R (2) (2)(8) ring motifs, respectively. The latter interaction results in chains of molecules along [100]. |
format | Online Article Text |
id | pubmed-3435589 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34355892012-09-11 Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2) N,O (1))copper(II) Petrusenko, Svitlana R. Belozub, Yaroslava I. Kokozay, Volodymyr N. Omelchenko, Irina V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(8)NO(3))(2)], the nearly planar molecule (r.m.s. deviation = 0.037 Å) is centrosymmetric with the Cu(II) atom lying on an inversion center. The Cu(II) atom is tetracoordinated, displaying a slightly distorted square-planar geometry. The main deviation from the ideal geometry is seen in the differences in the Cu—O [1.8833 (10) Å] and Cu—N [1.9405 (13) Å] bond lengths, while angular deviations are less than 3°. Intramolecular O—H⋯O and intermolecular Csp(2)—H⋯O hydrogen bonds form S(5) and R (2) (2)(8) ring motifs, respectively. The latter interaction results in chains of molecules along [100]. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435589/ /pubmed/22969462 http://dx.doi.org/10.1107/S1600536812032187 Text en © Petrusenko et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Petrusenko, Svitlana R. Belozub, Yaroslava I. Kokozay, Volodymyr N. Omelchenko, Irina V. Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2) N,O (1))copper(II) |
title | Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2)
N,O
(1))copper(II) |
title_full | Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2)
N,O
(1))copper(II) |
title_fullStr | Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2)
N,O
(1))copper(II) |
title_full_unstemmed | Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2)
N,O
(1))copper(II) |
title_short | Bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2)
N,O
(1))copper(II) |
title_sort | bis(2-hydroxyiminomethyl-6-methoxyphenolato-κ(2)
n,o
(1))copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435589/ https://www.ncbi.nlm.nih.gov/pubmed/22969462 http://dx.doi.org/10.1107/S1600536812032187 |
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