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Di-μ-chlorido-μ-(dimethyl sulfide)-bis{dichlorido[(dimethyl selenide-κSe)(dimethyl sulfide-κS)(0.65/0.35)]niobium(III)}(Nb—Nb)

The dinuclear compound, [Nb(2)Cl(6)(C(2)H(6)S)(1.7)(C(2)H(6)Se)(1.3)], features an Nb(III)=Nb(III) double bond [2.6878 (5) Å]. The molecule lies on a twofold rotation axis that passes through the middle of this bond as well as through the bridging dimethyl sulfide ligand. The Nb(III) ion exists in...

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Detalles Bibliográficos
Autores principales:	Matsuura, Masatoshi, Fujihara, Takashi, Nagasawa, Akira, Ng, Seik Weng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2012
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435590/ https://www.ncbi.nlm.nih.gov/pubmed/22969463 http://dx.doi.org/10.1107/S1600536812033673

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