Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]

The green title complex, [Co(2)(CH(3))(2)(C(12)H(21)N(2)Si)(2)], was obtained from bis­{[μ-N-tert-butyl­dimethyl­silyl-N-(pyridin-2-ylmeth­yl)amido]­chloridocobalt(II)} and methyl­lithium in diethyl ether at 195 K via a metathesis reaction. The dimeric cobalt(II) complex exhibits a crystallographic...

Descripción completa

Detalles Bibliográficos
Autores principales: Malassa, Astrid, Agthe, Christine, Görls, Helmar, Westerhausen, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435591/
https://www.ncbi.nlm.nih.gov/pubmed/22969464
http://dx.doi.org/10.1107/S1600536812032321
_version_ 1782242546962923520
author Malassa, Astrid
Agthe, Christine
Görls, Helmar
Westerhausen, Matthias
author_facet Malassa, Astrid
Agthe, Christine
Görls, Helmar
Westerhausen, Matthias
author_sort Malassa, Astrid
collection PubMed
description The green title complex, [Co(2)(CH(3))(2)(C(12)H(21)N(2)Si)(2)], was obtained from bis­{[μ-N-tert-butyl­dimethyl­silyl-N-(pyridin-2-ylmeth­yl)amido]­chloridocobalt(II)} and methyl­lithium in diethyl ether at 195 K via a metathesis reaction. The dimeric cobalt(II) complex exhibits a crystallographic center of inversion in the middle of the Co(2)N(2) ring (average Co—N = 2.050 Å). The Co(II) atom shows a distorted tetra­hedral coordination sphere. The exocyclic Co—N bond length to the pyridyl group shows a similar value of 2.045 (4) Å. The exocyclic methyl group has a rather long Co—C bond length of 2.019 (5) Å.
format Online
Article
Text
id pubmed-3435591
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34355912012-09-11 Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)] Malassa, Astrid Agthe, Christine Görls, Helmar Westerhausen, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The green title complex, [Co(2)(CH(3))(2)(C(12)H(21)N(2)Si)(2)], was obtained from bis­{[μ-N-tert-butyl­dimethyl­silyl-N-(pyridin-2-ylmeth­yl)amido]­chloridocobalt(II)} and methyl­lithium in diethyl ether at 195 K via a metathesis reaction. The dimeric cobalt(II) complex exhibits a crystallographic center of inversion in the middle of the Co(2)N(2) ring (average Co—N = 2.050 Å). The Co(II) atom shows a distorted tetra­hedral coordination sphere. The exocyclic Co—N bond length to the pyridyl group shows a similar value of 2.045 (4) Å. The exocyclic methyl group has a rather long Co—C bond length of 2.019 (5) Å. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435591/ /pubmed/22969464 http://dx.doi.org/10.1107/S1600536812032321 Text en © Malassa et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Malassa, Astrid
Agthe, Christine
Görls, Helmar
Westerhausen, Matthias
Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]
title Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]
title_full Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]
title_fullStr Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]
title_full_unstemmed Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]
title_short Bis[μ-N-(tert-butyl­dimethyl­silyl)-N-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(II)]
title_sort bis[μ-n-(tert-butyl­dimethyl­silyl)-n-(pyridin-2-ylmeth­yl)amido]­bis­[methyl­cobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435591/
https://www.ncbi.nlm.nih.gov/pubmed/22969464
http://dx.doi.org/10.1107/S1600536812032321
work_keys_str_mv AT malassaastrid bismntertbutyldimethylsilylnpyridin2ylmethylamidobismethylcobaltii
AT agthechristine bismntertbutyldimethylsilylnpyridin2ylmethylamidobismethylcobaltii
AT gorlshelmar bismntertbutyldimethylsilylnpyridin2ylmethylamidobismethylcobaltii
AT westerhausenmatthias bismntertbutyldimethylsilylnpyridin2ylmethylamidobismethylcobaltii

Ejemplares similares