Cargando…

cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)

In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl­pyridine (ppy) ligands and two Br(−) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435592/
https://www.ncbi.nlm.nih.gov/pubmed/22969465
http://dx.doi.org/10.1107/S160053681203471X
_version_ 1782242547209338880
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl­pyridine (ppy) ligands and two Br(−) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0 (3) and 47.3 (3)°. In the crystal, the complex mol­ecules are stacked in columns along the a axis. In the columns, there are numerous intra- and inter­molecular π–π inter­actions between the six-membered rings, the shortest ring centroid–centroid distance being 3.774 (6) Å.
format Online
Article
Text
id pubmed-3435592
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34355922012-09-11 cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl­pyridine (ppy) ligands and two Br(−) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0 (3) and 47.3 (3)°. In the crystal, the complex mol­ecules are stacked in columns along the a axis. In the columns, there are numerous intra- and inter­molecular π–π inter­actions between the six-membered rings, the shortest ring centroid–centroid distance being 3.774 (6) Å. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435592/ /pubmed/22969465 http://dx.doi.org/10.1107/S160053681203471X Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)
title cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)
title_full cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)
title_fullStr cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)
title_full_unstemmed cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)
title_short cis-Dibromidobis(2-phenyl­pyridine-κN)platinum(II)
title_sort cis-dibromidobis(2-phenyl­pyridine-κn)platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435592/
https://www.ncbi.nlm.nih.gov/pubmed/22969465
http://dx.doi.org/10.1107/S160053681203471X
work_keys_str_mv AT hakwang cisdibromidobis2phenylpyridineknplatinumii