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cis-Dibromidobis(2-phenylpyridine-κN)platinum(II)
In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenylpyridine (ppy) ligands and two Br(−) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435592/ https://www.ncbi.nlm.nih.gov/pubmed/22969465 http://dx.doi.org/10.1107/S160053681203471X |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenylpyridine (ppy) ligands and two Br(−) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0 (3) and 47.3 (3)°. In the crystal, the complex molecules are stacked in columns along the a axis. In the columns, there are numerous intra- and intermolecular π–π interactions between the six-membered rings, the shortest ring centroid–centroid distance being 3.774 (6) Å. |
format | Online Article Text |
id | pubmed-3435592 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34355922012-09-11 cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtBr(2)(C(11)H(9)N)(2)], the Pt(II) ion has a distorted cis-Br(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenylpyridine (ppy) ligands and two Br(−) anions. The ppy ligands are not planar, the dihedral angles between the pyridine and benzene rings being 49.0 (3) and 47.3 (3)°. In the crystal, the complex molecules are stacked in columns along the a axis. In the columns, there are numerous intra- and intermolecular π–π interactions between the six-membered rings, the shortest ring centroid–centroid distance being 3.774 (6) Å. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435592/ /pubmed/22969465 http://dx.doi.org/10.1107/S160053681203471X Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) |
title |
cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) |
title_full |
cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) |
title_fullStr |
cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) |
title_full_unstemmed |
cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) |
title_short |
cis-Dibromidobis(2-phenylpyridine-κN)platinum(II) |
title_sort | cis-dibromidobis(2-phenylpyridine-κn)platinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435592/ https://www.ncbi.nlm.nih.gov/pubmed/22969465 http://dx.doi.org/10.1107/S160053681203471X |
work_keys_str_mv | AT hakwang cisdibromidobis2phenylpyridineknplatinumii |