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Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)

In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra­hedral geometry and the other Ag(I) ion is coordinated by two N ato...

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Detalles Bibliográficos
Autores principales: Yeh, Chun-Wei, Ho, Yuh-Wen, Lee, Hsun-Tsing, Wang, Ju-Chun, Suen, Maw-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435593/
https://www.ncbi.nlm.nih.gov/pubmed/22969466
http://dx.doi.org/10.1107/S1600536812034721
Descripción
Sumario:In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra­hedral geometry and the other Ag(I) ion is coordinated by two N atoms from two L ligands in a bent arrangement [N—Ag—N = 169.03 (17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent Ag(I) ions, forming a trinuclear complex. One of the PF(6) (−) anions is half-occupied, with the P atom located on a twofold rotation axis. The PF(6) (−) anions link the complex mol­ecules via Ag⋯F inter­actions [2.80 (2) and 2.85 (2) Å] into a polymeric chain along [100].