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Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)

In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra­hedral geometry and the other Ag(I) ion is coordinated by two N ato...

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Autores principales: Yeh, Chun-Wei, Ho, Yuh-Wen, Lee, Hsun-Tsing, Wang, Ju-Chun, Suen, Maw-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435593/
https://www.ncbi.nlm.nih.gov/pubmed/22969466
http://dx.doi.org/10.1107/S1600536812034721
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author Yeh, Chun-Wei
Ho, Yuh-Wen
Lee, Hsun-Tsing
Wang, Ju-Chun
Suen, Maw-Cherng
author_facet Yeh, Chun-Wei
Ho, Yuh-Wen
Lee, Hsun-Tsing
Wang, Ju-Chun
Suen, Maw-Cherng
author_sort Yeh, Chun-Wei
collection PubMed
description In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra­hedral geometry and the other Ag(I) ion is coordinated by two N atoms from two L ligands in a bent arrangement [N—Ag—N = 169.03 (17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent Ag(I) ions, forming a trinuclear complex. One of the PF(6) (−) anions is half-occupied, with the P atom located on a twofold rotation axis. The PF(6) (−) anions link the complex mol­ecules via Ag⋯F inter­actions [2.80 (2) and 2.85 (2) Å] into a polymeric chain along [100].
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spelling pubmed-34355932012-09-11 Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate) Yeh, Chun-Wei Ho, Yuh-Wen Lee, Hsun-Tsing Wang, Ju-Chun Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra­hedral geometry and the other Ag(I) ion is coordinated by two N atoms from two L ligands in a bent arrangement [N—Ag—N = 169.03 (17)°]. Two L ligands adopt a syn conformation, while the other two adopt an anti conformation. They bridge adjacent Ag(I) ions, forming a trinuclear complex. One of the PF(6) (−) anions is half-occupied, with the P atom located on a twofold rotation axis. The PF(6) (−) anions link the complex mol­ecules via Ag⋯F inter­actions [2.80 (2) and 2.85 (2) Å] into a polymeric chain along [100]. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435593/ /pubmed/22969466 http://dx.doi.org/10.1107/S1600536812034721 Text en © Yeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yeh, Chun-Wei
Ho, Yuh-Wen
Lee, Hsun-Tsing
Wang, Ju-Chun
Suen, Maw-Cherng
Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)
title Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)
title_full Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)
title_fullStr Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)
title_full_unstemmed Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)
title_short Tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) N:N′]tris­ilver(I) tris­(hexa­fluoridophosphate)
title_sort tetra­kis[μ-1,3-bis­(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ(2) n:n′]tris­ilver(i) tris­(hexa­fluoridophosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435593/
https://www.ncbi.nlm.nih.gov/pubmed/22969466
http://dx.doi.org/10.1107/S1600536812034721
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