catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]

The Ag(I) atom in the polycationic salt, {[Ag(C(11)H(11)N(3)O)]NO(3)}(n), shows a linear coordination [N—Ag—N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO(3) (−) counter-ions surround the polym...

Descripción completa

Detalles Bibliográficos
Autores principales: Deng, Zhao-Peng, Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435594/
https://www.ncbi.nlm.nih.gov/pubmed/22969467
http://dx.doi.org/10.1107/S1600536812034769
_version_ 1782242547688538112
author Deng, Zhao-Peng
Gao, Shan
Ng, Seik Weng
author_facet Deng, Zhao-Peng
Gao, Shan
Ng, Seik Weng
author_sort Deng, Zhao-Peng
collection PubMed
description The Ag(I) atom in the polycationic salt, {[Ag(C(11)H(11)N(3)O)]NO(3)}(n), shows a linear coordination [N—Ag—N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO(3) (−) counter-ions surround the polymeric chain and inter­act only weakly with it [Ag⋯O = 2.701 (4) and 2.810 (5) Å]. Adjacent chains are linked into a three-dimensional network by O—H⋯O and N—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3435594
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34355942012-09-11 catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate] Deng, Zhao-Peng Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ag(I) atom in the polycationic salt, {[Ag(C(11)H(11)N(3)O)]NO(3)}(n), shows a linear coordination [N—Ag—N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO(3) (−) counter-ions surround the polymeric chain and inter­act only weakly with it [Ag⋯O = 2.701 (4) and 2.810 (5) Å]. Adjacent chains are linked into a three-dimensional network by O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435594/ /pubmed/22969467 http://dx.doi.org/10.1107/S1600536812034769 Text en © Deng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Zhao-Peng
Gao, Shan
Ng, Seik Weng
catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]
title catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]
title_full catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]
title_fullStr catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]
title_full_unstemmed catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]
title_short catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ(2) N (1):N (4))amino­meth­yl]phenol] nitrate]
title_sort catena-poly[[silver(i)-μ-2-[(pyrazin-2-yl-κ(2) n (1):n (4))amino­meth­yl]phenol] nitrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435594/
https://www.ncbi.nlm.nih.gov/pubmed/22969467
http://dx.doi.org/10.1107/S1600536812034769
work_keys_str_mv AT dengzhaopeng catenapolysilverim2pyrazin2ylk2n1n4aminomethylphenolnitrate
AT gaoshan catenapolysilverim2pyrazin2ylk2n1n4aminomethylphenolnitrate
AT ngseikweng catenapolysilverim2pyrazin2ylk2n1n4aminomethylphenolnitrate

Ejemplares similares