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{4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate

The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(2))]·H(2)O, comprises half of a Schiff base complex and half of a water mol­ecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the Cu(II) atom, located on a twofold axis, is distorte...

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Autores principales: Kargar, Hadi, Kia, Reza, Ganji, Fatemeh, Mirkhani, Valiollah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435595/
https://www.ncbi.nlm.nih.gov/pubmed/22969468
http://dx.doi.org/10.1107/S1600536812034502
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author Kargar, Hadi
Kia, Reza
Ganji, Fatemeh
Mirkhani, Valiollah
author_facet Kargar, Hadi
Kia, Reza
Ganji, Fatemeh
Mirkhani, Valiollah
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(2))]·H(2)O, comprises half of a Schiff base complex and half of a water mol­ecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the Cu(II) atom, located on a twofold axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)°. In the crystal, the water mol­ecule that is hydrogen bonded to the coordinated O atoms links the mol­ecules via O—H⋯O inter­actions into chains parallel to [001]. The crystal structure is further stabilized by C—H⋯π inter­actions, and by π–π inter­actions involving inversion-related chelate rings [centroid–centroid distance = 3.480 (4) Å].
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spelling pubmed-34355952012-09-11 {4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate Kargar, Hadi Kia, Reza Ganji, Fatemeh Mirkhani, Valiollah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(2))]·H(2)O, comprises half of a Schiff base complex and half of a water mol­ecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the Cu(II) atom, located on a twofold axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)°. In the crystal, the water mol­ecule that is hydrogen bonded to the coordinated O atoms links the mol­ecules via O—H⋯O inter­actions into chains parallel to [001]. The crystal structure is further stabilized by C—H⋯π inter­actions, and by π–π inter­actions involving inversion-related chelate rings [centroid–centroid distance = 3.480 (4) Å]. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435595/ /pubmed/22969468 http://dx.doi.org/10.1107/S1600536812034502 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Ganji, Fatemeh
Mirkhani, Valiollah
{4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title {4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_full {4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_fullStr {4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_full_unstemmed {4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_short {4,4′-Dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) monohydrate
title_sort {4,4′-dimethyl-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435595/
https://www.ncbi.nlm.nih.gov/pubmed/22969468
http://dx.doi.org/10.1107/S1600536812034502
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